Liquid crystals, which have high dielectric anisotropy even in the terahertz region and are easily controllable for dielectric permittivity by applying an electric field, have become increasingly attractive in recent years. The non-radiative dielectric (NRD) waveguide has a structure in which a dielectric line is sandwiched between two metal plates and by replacing the dielectric part with liquid crystal, a low loss liquid crystal-loaded NRD waveguide type terahertz phase shifter can be obtained. However, since the thickness of the liquid crystal layer is several hundred micrometers, it has a response time of as long as several hundred seconds when the driving voltage is removed. It is necessary to devise improvements for practical application. By inserting two polyethylene terephthalate (PET) films and reducing the thickness of the liquid crystal layer, the decay time was improved well, but the phase change was significantly reduced. In this study, we report improving both decay time and phase change with aligned nanofiber/liquid crystal complex. In addition, we demonstrate liquid crystal-load phase shifter, which has 360° phase change and the response time below one second.