Self-assembled two-dimensional salicylaldimine lanthanum(III) nitrate coordination polymer

Radecka‐Paryzek, Wanda; Pospieszna-Markiewicz, Izabela; Kubicki, Maciej

doi:10.1016/j.ica.2006.07.071

Cited by 64 publications

(19 citation statements)

References 39 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The profile and magnitude of band splitting associated with asymmetric nitrate vibrations, which is indicative of the interaction strength between the metal and the oxygen atoms of the nitrates, is consistent with the presence of the nitrate groups coordinating in a bidentate fashion. [8,9] The photophysical properties of lanthanide complexes containing H 2 L formed in situ in a one-step, metal-promoted condensation of aldehyde and diamine precursors were related to the behavior of this ligand in the free form obtained separately for comparison purposes.…”

Section: Resultsmentioning

confidence: 99%

“…[8] This species, which self-assembles into a 2D coordination polymer, is obtained in situ in a onestep, metal-promoted condensation of salicylaldehyde with 1,4-butanediamine (putrescine, a biogenic amine). It displays infinite polymeric structure composed of networks of 10-coordinated lanthanum nodes linked by bridging unionized N,NЈ-bis(salicylidene)-1,4-butanediamine ligands that utilize only hydroxy oxygen atoms for coordination while the nitrogen atoms remain uncoordinated.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Self‐Assembled Lanthanide Salicylaldimines with a Unique Coordination Mode

et al. 2010

Self Cite

View full text Add to dashboard Cite

New lanthanide salicylaldimine complexes of the formula [Ln(H2L)3(NO3)3](H2L), where Ln = La3+ (1), Nd3+ (2), Eu3+ (3), Gd3+ (4), Ho3+ (5), Er3+ (6), Tb3+ (7) or Yb3+ (8), and H2L = N,N′‐bis(salicylidene)‐4‐methyl‐1,3‐phenylenediamine, were formed in a self‐assembly process involving the lanthanide template‐induced one‐step [2+1] Schiff base condensation reaction between salicylaldehyde and 4‐methyl‐1,3‐phenylenediamine. The unusual coordination pattern of salen‐type ligands in these complexes, in which the three potentially tetradentate N2O2 salicylaldimines function as undeprotonated, monodentate, exclusively O‐donor ligands without involving the nitrogen atoms in the coordination environment, was proved by single‐crystal X‐ray diffraction analysis and correlated with spectroscopic characterization. In this species with the nine‐coordinate distorted tricapped trigonal prism geometry, the nitrates act as bidentate chelators occupying six coordination sites and leaving the remaining sites available for salicylaldimine ligands formed in situ in the template process. The additional salicylaldimine molecule acts as a guest for the salicylaldimine complex host and stabilizes the overall self‐assembled supramolecular network.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Self‐Assembled Lanthanide Salicylaldimines with a Unique Coordination Mode

et al. 2010

Self Cite

View full text Add to dashboard Cite

show abstract

“…Such a 2D structure from dinuclear units with two bridge-linking models is new among the numerous Salen-type lanthanide complexes. It is different from 2D network complex [Dy 2 (hmi) 2 (NO 3 ) 2 (MeOH) 2 ] n [7], a dinuclear Dy(III) SMM is bridged by phenoxide groups, and also different from the 2D coordination polymer [La 2 (L) 4 (NO 3 ) 6 ] (L = N,N′-bis(salicylidene)-1,4-butanediamine) with ligand-bridging dimer [12]. Notably, complex 1 is a rare example of μ 2 -(methoxy-O) 2 bridged dinuclear dysprosium complex [13].…”

mentioning

confidence: 89%

Single molecule magnet of 2D Salen-type dysprosium coordination polymer

Yue

Yan

Sun

et al. 2015

Inorganic Chemistry Communications

View full text Add to dashboard Cite

“…5 The antitumor, antiviral, antifungal and antibacterial properties of these compounds means they have found applications in medicine and pharmacy. 6 Due to these biological properties, Schiff bases are used as basic materials for the synthesis of many drugs. 7 It has also been reported that Schiff bases of salicylaldehydes show some antimicrobial activity.…”

Section: Introductionmentioning

confidence: 99%

Experimental and theoretical study of antioxidative properties of some salicylaldehyde and vanillic Schiff bases

et al. 2015

View full text Add to dashboard Cite

The antioxidative capacity and structure-activity relationships of ten Schiff bases were investigated experimentally and theoretically. All compounds contain the aniline moiety, while the aldehyde part is either salicylaldehyde or vanillin. The DPPH assay was used to test the potential antioxidative activity of these compounds, and DFT study was used to investigate their electronic structures and provide insight into their structure-activity relationships. The effect of the position of the hydroxy, as well other groups present, on the antioxidative activity was examined. The possible radical scavenging mechanism was determined in polar (water and methanol), and nonpolar (benzene) solvents. Based on the experimental and computational results, compounds 7 and 8 exhibit the highest radical scavenging properties.

show abstract

Self-assembled two-dimensional salicylaldimine lanthanum(III) nitrate coordination polymer

Cited by 64 publications

References 39 publications

Self‐Assembled Lanthanide Salicylaldimines with a Unique Coordination Mode

Self‐Assembled Lanthanide Salicylaldimines with a Unique Coordination Mode

Single molecule magnet of 2D Salen-type dysprosium coordination polymer

Experimental and theoretical study of antioxidative properties of some salicylaldehyde and vanillic Schiff bases

Contact Info

Product

Resources

About