Self-assembling iron and manganese metal–germanium–selenide frameworks: [NMe4]2MGe4Se10, where M = Fe or Mn

Reactivity of Chalcogenostannate Compounds: Syntheses, Crystal Structures, and Electronic Properties of Novel Compounds Containing Discrete Ternary Anions [MII4(μ4-Se)(SnSe4)4]10- (MII = Zn, Mn)

“…[1][2][3] In addition to a range of coordination compounds, from [PPh 4 ] 4 [E′ 2 (ME 4 ) 4 ] (E′ ) Sn, M ) W, E ) S, 4 or E′ ) Sn, Pb; M ) W, Mo; E ) Se 5 ) to organometallic species such as [(CO) 6 Fe 2 (Sb 2 S 6 )][SbS 6 ] 2 ‚2SO 2 6 or [(PhSnS 3 ) 2 (CuPPhMe 2 ) 6 ], 7 several ternary or quaternary phases also attracted attention owing to novel structural, optoelectronic or magnetic properties; [8][9][10][11][12] 15 (A ) Na, K; E′ ) Ge, Sn; E ) S, Se) as synthons.…”

Three‐Dimensional Frameworks of Gallium Selenide Supertetrahedral Clusters

“…Not only are there few 3D open-framework selenides, the types of supertetrahedral selenide clusters are also limited. [9][10][11] For example, although T5 sulfide clusters with as many as 35 metal atoms (e.g., Cu 5 In 30 S 56…”

Structural characterization of heteropolymeric iron and main group metal complexes

“…The red tetragonal (NMe 4 )Fe(S) 10 Ge 4 was studied by three groups (Achak et al , 1996 ;Bowers et al , 1996 ;Akari et al , 1998 ), the crystallographic and structural data are in good agreement. The sulfur atoms bridged to metal atoms and are tetrahedrally coordinated [Fe(II)S 4 , Ge(IV)S 4 ] with mean M-S bond distances of 2.37 (M = Fe) and 2.19 (M = Ge).…”

“…The iron atoms exist in the oxidation states 0, + 2 and + 3, from which + 3 by far prevails. The inner coordination sphere about iron atoms are Fe (0) (Achak et al , 1996 ), Hg (Sosinski et al , 1983 ), FeC 10 (Mammano et al , 1977 ;Graziani et al , 1980 ;Yukle et al , 1996 ), FeC 3 HBr 2 (Enland et al , 1997 )]; Fe(II): [FeN 3 ( H ö hn et al, 1991 ), FeS 4 (Achak et al , 1996 ;Bowers et al , 1996 ;Akari et al , 1998 ), FeC 6 (Adam et al , 1990 ;Behrens et al , 1991 ;Schwarz et al , 1996 ;Yian et al , 1996 ), FeN 5 O and FeN 4 O 2 (Cingi et al , 1985 )]; Fe(III): [FeC 5 N (Castellano et al, 1977, Kl ü fers andHauss ü l, 1985 ;Mulliza et al , 1990 ;Navaza et al , 1990 ;Johnson et al , 1991 ), FeC 6 (Mayer and Pichard , 1988 ;Meyer and Pickerdt , 1989 ;Swartner et al , 1997 ), FeO 4 N 2 (Pavel č í k and Kettmann, 1983 ), FeO 6 (Burger and Kl ü fers, 1966a,b ;Calogero et al , 1977 ), FeO 5 N 2 (Cohen and Hoard , 1966 ;Solans et al , 1984a,b ), and FeO 4 N 3 (Chuklianova et al , 1981 )]. The mean Fe(0)-L bond distance elongated in the order: 1.69 ( μ -H) < 1.78 ( μ -CO) < 2.045 (C, cp) < 2.317 (Zn) < 2.522 (Hg) < 2.627 (In) < 2.641 (Bi).…”

“…The sulfur atoms bridged to metal atoms and are tetrahedrally coordinated [Fe(II)S 4 , Ge(IV)S 4 ] with mean M-S bond distances of 2.37 (M = Fe) and 2.19 (M = Ge). For red brown (NMe 4 ) 2 Fe(S) 10 Ge 4 (Akari et al , 1998 ), only crystallographic data are available. In another red brown tetragonal Cs 2 Fe(S) 10 Ge (Bowers et al , 1996 ), the sulfur atoms serve as bridges between metal atoms and form a polymeric structure.…”