Self-Assembly Mechanisms of Triblock Janus Particles

Abstract

We present a detailed model to study the nucleation of triblock Janus particles from solution. The Janus particles are modeled as cross-linked polystyrene spheres whose poles are patched with sticky alkyl groups and their middle band is covered with negative charges. To mimic the experimental conditions, solvent, counterions, and a substrate, on which the crystallization takes place, are included in the model. A many-body dissipative particle dynamics simulation technique is employed to include hydrodynamic and many-body interactions. Metadynamics simulations are performed to explore the pathways for nucleation of Kagome and hexagonal lattices. In agreement with experiment, we found that nucleation of the Kagome lattice from solution follows a two-step mechanism. The connection of colloidal particles through their patches initially generates a disordered liquid network. Subsequently, orientational rearrangements in the liquid precursors lead to the formation of ordered nuclei. Biasing the potential energy of the largest crystal, a critical nucleus appears in the simulation box, whose further growth crystallizes the whole solution. The location of the phase transition point and its shift with patch width are in very good agreement with experiment. The structure of the crystallized phase depends on the patch width; in the limit of very narrow patches strings are stable aggregates, intermediate patches stabilize the Kagome lattice, and wide patches nucleate the hexagonal phase. The scaling behavior of the calculated barrier heights confirms a first-order liquid-Kagome phase transition.

The Influence of Initiator Concentration on Selected Properties on Poly-N-Vinylcaprolactam Nanoparticles

“…Aggregation occurs rapidly up to a certain point and then the changes of read-out values of the hydrodynamic diameter take place mildly. Theoretically, high perturbations, including initiator concentration, may result in rapid phase transitions and, hence, larger aggregates of the condensed phase, as it was presented by Eslami et al [29,30]. This may indicate that after the system has reached a certain temperature, aggregation is probably limited.…”

Molecular Dynamics Simulations of Crystal Nucleation near Interfaces in Incompatible Polymer Blends

“…The error bars represent the 95% confidence intervals of the fitting parameters. We notice that the critical nucleus of PE is much smaller than the critical nucleus of molecules with roughly isotropic shapes, such as LJ liquids and colloidal particles [ 51 , 52 ]. The rather small critical nucleus size of PE may result from the deep supercooling and the multi-stage crystal nucleation of polymers.…”

Molecular Dynamics Simulation of the Ionic Liquid 1‐n‐Butyl‐3‐Methylimidazolium Methylsulfate [Bmim][MeSO4]: Interfacial Properties at the Silica and Vacuum Interfaces

“…Computer simulation techniques, on the other hand, are regarded as powerful tools for examining the microscopic picture of complex fluids at the interface . Over the past two decades varieties of aspects of ILs at the interface have been investigated using molecular simulation methods.…”