Self-assembly of monomeric porphyrin molecules into nanostructures: Self-assembly pathways and applications for sensing and environmental treatment

First 4,7-oxygenated 1,10-phenanthroline-2,9-diamides: synthesis, tautomerism and complexation with REE nitrates

“…The phenomenon of self-assembly of organic molecules is well documented. [41][42][43][44][45] Experimental section…”

Near-infrared fluorescence probes based on disassembly-induced emission pyrene derivatives

“…Supramolecular self-assembly is a simple method to control the behavior of luminescent target molecules by forming new aggregates through intermolecular non-covalent bonding interactions. 24–28 In particular, host–guest interactions are widely used to modulate the position of fluorescence peak and the emission intensity of molecules to develop a variety of smart, tunable fluorescent materials. The synthesis process can be simplified by utilizing this strategy to regulate the emission properties of the host molecules.…”

In Situ Synthesis of Porphyrin-Based Hyper-Cross-Linked Sub-nanometer Porous Polymer for Carbon Dioxide Adsorption Applications

“…In porous polymers, porphyrin has attracted attention due to its rigid structure, which allows for the creation of materials with permanent porosity . Numerous instances in the literature have shown the integration of porphyrins into polymer structures, as illustrated in Figure b. ,,, Two primary strategies have been documented: (1) Encapsulating porphyrins within the pores. Nonetheless, this approach compromises the overall porosity of the material .…”

“…19 (ii) The second approach involves incorporating porphyrin as a building block, which leads to the creation of porous materials with porphyrin integrated into their structure. 1,20,21 This alternative approach has the advantage of ensuring accessibility of porphyrins and preventing their aggregation. 22 This project will concentrate on creating hypercross-linked polymers renowned for their enduring porosity, exceptional stability, and versatility across various applications.…”

“…1 Numerous instances in the literature have shown the integration of porphyrins into polymer structures, as illustrated in Figure 1b. 16,21,26,27 Two primary strategies have been documented: (1) Encapsulating porphyrins within the pores. Nonetheless, this approach compromises the overall porosity of the material.…”