Self-Assembly of Nanometer-Scale Secondary Building Units into an Undulating Two-Dimensional Network with Two Types of Hydrophobic Cavity

Bourne, Susan A.; Lu, Joan; Mondal, Arunendu; Moulton, Brian; Zaworotko, Michael J.

doi:10.1002/1521-3773(20010601)40:11<2111::aid-anie2111>3.0.co;2-f

Cited by 353 publications

(26 citation statements)

References 26 publications

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“…The synthesis of copper( II )‐based MOFs also attracted much attention 38, 39, 52–61. The first Cu–organic framework is HKUST‐1 (also called CuBTC, where BTC = 1,3,5‐benzene tricarboxylate), which was invented by Williams et al52 and subsequently studied by numerous research groups 38, 39, 53–57. HKUST‐1, which is composed of Cu II paddlewheel clusters linked by trigonal benzene‐1,3,5‐tricarboxylate, possesses a face‐centered‐cubic crystal that contains an intersecting 3D system of a bimodal pore size distribution with a BET surface area of about 1500 m 2 g −1 .…”

Section: Hydrogen Storage In Mofs At a Low Temperature Of 77 Kmentioning

confidence: 99%

Hydrogen Storage in Metal–Organic Frameworks

2010

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Metal–organic frameworks (MOFs) are highly attractive materials because of their ultra‐high surface areas, simple preparation approaches, designable structures, and potential applications. In the past several years, MOFs have attracted worldwide attention in the area of hydrogen energy, particularly for hydrogen storage. In this review, the recent progress of hydrogen storage in MOFs is presented. The relationships between hydrogen capacities and structures of MOFs are evaluated, with emphasis on the roles of surface area and pore size. The interaction mechanism between H2 and MOFs is discussed. The challenges to obtain a high hydrogen capacity at ambient temperature are explored.

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Section: Hydrogen Storage In Mofs At a Low Temperature Of 77 Kmentioning

confidence: 99%

Hydrogen Storage in Metal–Organic Frameworks

2010

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“…[19][20][21][22][23][24][25][26][27][28][29][30] In particular, the benzenedicarboxylic acids have been found to be the ideal ligands for designing coordination polymers and open framework structures. 1-9, 13 Cyclohexanedicarboxylic acids would similarly be expected to be useful ligands, considering that they also occur in different conformations. There have, however, been very few metal cyclohexanedicarboxylates (CHDCs) reported in the literature.…”

Section: Introductionmentioning

confidence: 99%

1, 2-, 1, 3- and 1, 4-Cyclohexanedicarboxylates of Cd and Mn with chain and layered structures

2006

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A systematic study has been carried out on the three isomeric cyclohexanedicarboxylates (CHDCs) formed by cadmium and manganese with the three isomeric dicarboxylic acids, in the presence or absence of amines. The CHDCs have been prepared under hydrothermal conditions and their structures established by X-ray crystallography. We have been able to isolate two-dimensional layered structures of 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates and chain structures of 1,3- and 1,4-cyclohexanedicarboxylates. The infinite metal-oxygen-metal linkages are observed only in the case of the 1,2-dicarboxylate. In all the three isomeric cyclohexanedicarboxylates, the e,e conformation is most favored, although the 1,4-CHDCs often contain rings in both the e,e and the a,e conformations.

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“…Benzenedicarboxylic acids have been used for designing coordination polymers and open framework structures. [16][17][18][19][20][21][22][23][24][25] Cyclohexanedicarboxylic acids (chdcH 2 ) can also be used as useful ligands, and considered their different conformations. In 1,2-chdcH 2 , the (e,e) and (a,e) conformers are known as the cis isomers, and the (a,a) conformer is known as the trans isomer.…”

Section: Structure Description Of 5 2-dmentioning

confidence: 99%