Switching arc characterization, e.g., measuring the arc voltage and current, is crucial for assessing the performance of power switchgears under different working conditions. This is especially challenging for short circuit current making as one of the most severe operations for medium voltage load break switches (MV-LBS). By closing the switch, a short circuit current flows through the arc which is ignited by the electrical breakdown in the gap between contacts before the contacts touch. This results in an abrupt change from the rated voltage of the power network, i.e., tens of thousands of volts, to the switching arc voltage, i.e., a few tens of volts and ultimately zero when the contacts touch. The inherent response of the measurement system to this very large step preceding the arc formation overlaps with the switching arc voltage and results in unrealistic arc voltages which makes correction of the distorted voltage waveform necessary.In this paper, a post processing method based on deconvolution correction technique, i.e. deconvolution of the measured voltage in time and frequency domains, is examined using experimentally determined impulse responses of the measurement system. To demonstrate its effectiveness, this method is applied to three different measurement system configurations with various step responses. The results show practically identical deconvoluted (corrected) voltage waveforms in all three measurement systems, although the directly measured waveforms have significant differences. The corrected arc voltage waveforms are in agreement with the indirect measurements proposed in previous studies.