2012
DOI: 10.1039/c1ce06086d
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Self-catalytic growth of hierarchical In2O3nanostructures on SnO2nanowires and their CO sensing properties

Abstract: Brush-like hierarchical In 2 O 3 nanostructures on SnO 2 nanowires have been synthesized by a two-step thermal vapor transport process. To elucidate the growth mechanism, the structural evolution of hierarchical In 2 O 3 nanostructures during the synthesis process was carefully examined. The experimental results showed that a self-catalytic vapor-liquid-solid (VLS) growth mechanism was responsible for the growth of hierarchical In 2 O 3 nanostructures. Compared with the film counterparts, the hierarchical In 2… Show more

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Cited by 30 publications
(15 citation statements)
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“…This is attributable to a reaction between the reducing gas molecules and adsorbed negative oxygen species occurring more easily than the oxygen to overcome the barrier to repopulating the vacant states of the oxide surfaces after desorption of oxygen on exposure to a reducing gas ambient [ 28 ]. Several oxide heterostructures have been found to show a recovery time longer than the response time in cyclic reducing gas-sensing tests [ 17 , 29 ]; this difference is associated with the high surface-to-volume ratio of nanostructures. In the current study, a larger surface area and the presence of heterointerfacial contact in the ZnO–ZFO heterostructures resulted in a higher acetone gas-sensing response and a shorter response time compared with those of pure ZnO; the recovery times differed only slightly.…”
Section: Resultsmentioning
confidence: 99%
“…This is attributable to a reaction between the reducing gas molecules and adsorbed negative oxygen species occurring more easily than the oxygen to overcome the barrier to repopulating the vacant states of the oxide surfaces after desorption of oxygen on exposure to a reducing gas ambient [ 28 ]. Several oxide heterostructures have been found to show a recovery time longer than the response time in cyclic reducing gas-sensing tests [ 17 , 29 ]; this difference is associated with the high surface-to-volume ratio of nanostructures. In the current study, a larger surface area and the presence of heterointerfacial contact in the ZnO–ZFO heterostructures resulted in a higher acetone gas-sensing response and a shorter response time compared with those of pure ZnO; the recovery times differed only slightly.…”
Section: Resultsmentioning
confidence: 99%
“…For the synthesis of tin oxide (SnO 2 ) nanowires, a custom physical vapor deposition process (PVD) was used. It mainly consisted of an evaporation–condensation process based on the vapor liquid solid (VLS) mechanism [64,65,66,67].…”
Section: Methodsmentioning
confidence: 99%
“…Recently, many heterostructure composites such as SnO 2 /ZnO [ 19 , 20 ], TiO 2 /SnO 2 [ 21 ], SnO 2 /Fe 2 O 3 [ 22 ] have been prepared to be applied as gas sensing materials to obtain the sensitive and selective gas sensors. In 2 O 3 and SnO 2 heterostructure composites have also been synthesized to enhance the properties of sensors [ 23 , 24 , 25 ]. In 2 O 3 /SnO 2 heterojunction microstructures synthesized by a facile room temperature solid-state reaction route exhibited high response to chlorine [ 26 ].…”
Section: Introductionmentioning
confidence: 99%