The Vlasov equilibrium in the electrostatically plugged tandem mirror machine with double cusps MM-4U is discussed. The plasma potential, density, and non-neutrality profiles are obtained by solving the Poisson–Maxwell equations on the basis of a solution of the Vlasov equation in equilibrium. The truncation conditions of the energy of plasma particles are included. The results show that the potential reaches a maximum and the density gets a minimum at the throat of the machine, i.e., at z = ±0.36 m. This consorts with the experimental measurements. The non-neutrality profiles show that there are four ion wells in the machine, two at the throats and another two at the centers of cusp.