1971
DOI: 10.1103/physrevb.3.2445
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Self-Diffusion in Potassium

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Cited by 59 publications
(23 citation statements)
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“…This interpretation is consistent with the observation (Mundy 1971) that the activation volume of the high-temperature process is about twice that of the lowtemperature process. The problem with this interpretation is that it is the intermediate temperature mechanism in the case of the threemechanism fit or the high temperature mechanism in the case of the two-mechanism fit that has diffusion parameters typical of vacancy diffusion in terms of the size of D o and the relation of Q to the melting temperature.…”
Section: D Feit Onsupporting
confidence: 90%
See 1 more Smart Citation
“…This interpretation is consistent with the observation (Mundy 1971) that the activation volume of the high-temperature process is about twice that of the lowtemperature process. The problem with this interpretation is that it is the intermediate temperature mechanism in the case of the threemechanism fit or the high temperature mechanism in the case of the two-mechanism fit that has diffusion parameters typical of vacancy diffusion in terms of the size of D o and the relation of Q to the melting temperature.…”
Section: D Feit Onsupporting
confidence: 90%
“…metals was rather more complicated than that in the close-packed metals. More recently, careful self-diffusion measurements in sodium (Mundy 1971) and potassium (Mundy, Miller and Porte 1971) have demonstrated non-Arrhenius behaviour, indicating that the division of b.c.c. metals into normal and anomalous diffusers is rather arbitrary, as was suggested by Peterson (1968).…”
Section: Introductionmentioning
confidence: 97%
“…P) This is the lowest temperature at which self-diffusion data exist [51], the selection of this temperature has been made for the same reasons as mentioned in h). 9) [47]; the correction from Bs to B has been made using the specific heat data of [48]. [57]; the entropy is obtained from Do = 1.71 cm2/s by using vD = 6.8 x 10l2 s-l. Potassium.…”
mentioning
confidence: 99%
“…They may originate from fundamental aspects involving the atomic migration mechanism up to effects associated with micro-structural characteristics. The defect diffusion deviating from the Arrhenius relation has been reported for normal metals such as potassium 10 and silver, 11 as well as the anomalous metals such as b-titanium. 12 Frequently, these deviations have been attributed to simultaneous effects of two or more different defects 2011) which contributed to the diffusion process.…”
mentioning
confidence: 99%