“…Heterogeneous liquid-solid materials can be constructed by self-assembly of materials derived from molecules [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 ]. Self-assembly involves the noncovalent bond formation, which has several advantages compared with the covalent bond formation: (1) Various shapes and structures of self-assembly materials can be formed by tuning the molecular structures; (2) diverse mechanisms of noncovalent bond formation can be used, including hydrogen-bonding, electrostatic interactions, van der Waals interactions, solvophobic interactions, π-π interactions and dipole-dipole interactions; (3) various spatial interactions including point-to-point, point-to-fiber, fiber-to-fiber, fiber-to-face and face-to-face modes are available, which are not restricted to the point-to-point interactions, that characterize covalent bond formation; (4) properties of the interactions can be affected largely by conditions such as temperature, concentration, light and chemical substances; (5) self-assembly materials can be degraded without using much energy and the constituent molecules may be recovered and reused.…”