Pervasive knowledge service is the service to people-oriented. Drawing lessons from the basic theory about field in physics and based on pervasive knowledge service space (PKS 2), the paper constructs the model of pervasive knowledge service field by means of multidisciplinary research achievements such as intelligence computing, pervasive computing, ecology, system science, knowledge science and service science, and discusses the ecology characteristics of pervasive knowledge service field. At the same time, the key technologies of pervasive knowledge service in design and implementation are discussed as well.