Tactile-based sensing technology represents one of the most promising methods for interacting with their surrounding environment. Consequently, flexible tactile sensing has garnered significant attention from researchers worldwide. In this study, triboelectricity and piezoelectricity were combined to propose a multifunctional self-powered tactile sensor (MSPTS). Notably, new and innovative self-healing electrodes were embedded and synthesized from HPDMS (poly(dimethylsiloxane)) and boric acid in the MSPTS, MSPTS demonstrated a linear detection range of 0.25−5 kPa with a sensitivity of 246.28 mV/kPa, indicating substantial improvements in sensor sensitivity, output performance, and anti-interference capability. Our method of forming hydrogen bonds between a self-healing material (SHM) and a liquid metal (LM) effectively addressed the issue of LM leakage within the flexible matrix under pressure, thus preventing sensor failure. The borate dynamic bonding conferred self-healing properties to the electrode when it was damaged. The MSPTS was successfully applied to pressure detection, material identification, and human body movement detection, significantly broadening the application range of flexible electronic devices.