Self‐sacrificial Templated Synthesis of Fe/N Co‐doping TiO<sub>2</sub> for Enhanced CO<sub>2</sub> Photocatalytic Reduction

Liu, Tao; Qileng, Aori; Wubulikasimu, Nuermaimaitijiang; Liu, Zhixiong; Liu, Weipeng; Liu, Yingju

doi:10.1002/cnma.202300343

Cited by 4 publications

(3 citation statements)

References 59 publications

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“…The possible pathway by which the catalyst reduces CO 2 to CH 4 is shown in Figure 3e. Liu et al 91 synthesized Fe,N-codoped TiO 2 photocatalytic materials (Fe x Ti@C) by injecting selfsacrificing templates (NH 2 -MIL-125(Ti)) in a Fe 3+ solution by calcination. The Fe 0.8 Ti@C catalyst had the highest CH 4 yield of 5.22 μmol h −1 g −1 , which was 7.8 times that of the original TiMOF template and 10.2 times that of the undoped Ti@C catalyst.…”

Section: Modification Strategies Of Tiomentioning

confidence: 99%

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Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook

Chen,

Li,

et al. 2024

Energy Fuels

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Carbon dioxide (CO 2 ) is one of the main causes of global warming. Scientists have found that the photocatalytic conversion of CO 2 using visible light can not only reduce CO 2 emissions and thus mitigate the rise of CO 2 concentration in the atmosphere but also produce high-value compounds and fuels, such as CH 4 , CO, HCOOH, and CH 3 OH. TiO 2 -based modified photocatalytic materials have the advantages of high performance and good chemical stability, so they have broad application potential in the field of CO 2 photocatalysis. So far, a lot of research has been done on the way of photocatalytic reaction and the development of materials, but these achievements still have a long way to go for practical engineering applications, and the modification of TiO 2 groups may be one of the ways to promote its engineering application ability. For this reason, this paper reviews the modification measures of defect engineering, photosensitization, heterojunctions, and so on, hoping to be helpful in follow-up research work in the fields of improving the performance of devices, improving the utilization of visible light, reducing the carrier recombination rate, and changing the efficiency of photocatalytic reduction. Among various modification methods, defect engineering and photosensitization have been applied, but heterojunction construction is still the most effective way to improve the reduction rate. Therefore, in this review, we mainly focus on the construction of heterojunctions to improve the reduction rate, especially on the progress of charge transfer mechanism of different heterojunctions. By summarizing the current research status, the future development of heterojunctions is reasonably considered and speculated.

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Section: Modification Strategies Of Tiomentioning

confidence: 99%

“…Copyright 2023 Elsevier. (f) Schematic diagram of the mechanism of photocatalytic reduction to CH 4 at Fe 0.8 Ti@C. This figure was reprinted with permission from ref . Copyright 2023 John Wiley and Sons.…”

Section: Modification Strategies Of Tio2mentioning

confidence: 99%

Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook

Chen,

Li,

et al. 2024

Energy Fuels

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“…TiO 2 is one of the most common catalysts in photocatalytic reactions. Liu et al [70] successfully prepared an Fe-N co-doped TiO 2 heterojunction photocatalyst (FeTi@C). The results show that the catalyst has a small band gap and excellent visible light absorption.…”

Section: Synergistic Effects Of Compound Defectsmentioning

confidence: 99%

A Review of the Effect of Defect Modulation on the Photocatalytic Reduction Performance of Carbon Dioxide

Zuo,

Tang,

Wang

et al. 2024

Molecules

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Constructive defect engineering has emerged as a prominent method for enhancing the performance of photocatalysts. The mechanisms of the influence of defect types, concentrations, and distributions on the efficiency, selectivity, and stability of CO2 reduction were revealed for this paper by analyzing the effects of different types of defects (e.g., metallic defects, non-metallic defects, and composite defects) on the performance of photocatalysts. There are three fundamental steps in defect engineering techniques to promote photocatalysis, namely, light absorption, charge transfer and separation, and surface-catalyzed reactions. Defect engineering has demonstrated significant potential in recent studies, particularly in enhancing the light-harvesting, charge separation, and adsorption properties of semiconductor photocatalysts for reducing processes like carbon dioxide reduction. Furthermore, this paper discusses the optimization method used in defect modulation strategy to offer theoretical guidance and an experimental foundation for designing and preparing efficient and stable photocatalysts.

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An Overview of Carbon Dioxide Photo/Electrocatalyzed by Titanium Dioxide Catalyst

Wang,

Xiong,

Guo

et al. 2024

ChemCatChem

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This study provides a comprehensive review of recent advancements in photocatalytic and electrocatalytic carbon dioxide reduction using titanium dioxide catalysts. The basic concepts of light absorption, electron transport, and reduction processes are introduced in this paper, which also delves into the specifics of photocatalytic and electrocatalytic reduction of carbon dioxide. The paper highlights the key applications and benefits of titanium dioxide, including its strong stability, outstanding light absorption capacity, and good electron transport performance, in the photocatalytic and electrocatalytic reduction of carbon dioxide. Furthermore, it examines the impact of various surface modification techniques on catalytic performance, as well as the effects of various titanium dioxide catalyst forms on catalytic activity and selectivity in carbon dioxide reduction. The in‐depth analysis exhibit promising catalytic properties and hold significant potential for future advancements. However, some obstacles still need to be overcome, such as increasing catalytic activity and selectivity while minimizing energy dissipation. Additionally, the paper provides a scientific foundation for accomplishing sustainable carbon conversion, it also calls for additional experimental and theoretical research into the mechanism of action for titanium dioxide catalyst.

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Self‐sacrificial Templated Synthesis of Fe/N Co‐doping TiO₂ for Enhanced CO₂ Photocatalytic Reduction

Cited by 4 publications

References 59 publications

Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook

Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook

A Review of the Effect of Defect Modulation on the Photocatalytic Reduction Performance of Carbon Dioxide

An Overview of Carbon Dioxide Photo/Electrocatalyzed by Titanium Dioxide Catalyst

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Self‐sacrificial Templated Synthesis of Fe/N Co‐doping TiO2 for Enhanced CO2 Photocatalytic Reduction

Cited by 4 publications

References 59 publications

Photocatalytic Reduction of CO2 by TiO2 Modified Materials: Recent Advances and Outlook

Photocatalytic Reduction of CO2 by TiO2 Modified Materials: Recent Advances and Outlook

A Review of the Effect of Defect Modulation on the Photocatalytic Reduction Performance of Carbon Dioxide

An Overview of Carbon Dioxide Photo/Electrocatalyzed by Titanium Dioxide Catalyst

Contact Info

Product

Resources

About

Self‐sacrificial Templated Synthesis of Fe/N Co‐doping TiO₂ for Enhanced CO₂ Photocatalytic Reduction

Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook

Photocatalytic Reduction of CO₂ by TiO₂ Modified Materials: Recent Advances and Outlook