Self‐Suspended Nanoparticles for N‐Alkylation Reactions: A New Concept for Catalysis

Abstract

The catalytic activity of snowman‐like and core‐shell Fe3O4/Au nanoparticles (NPs), obtained through a “wet chemistry” approach which directly restitutes nanocatalysts stable and highly active in the reaction medium, was tested towards N‐alkylation reactions. The nanocatalysts were tested for the synthesis of secondary amines. The core‐shell NPs, thanks to the surface properties, homogeneous dispersion and intimate connection with reagents in the catalyst medium, exhibited an excellent catalytic activity (e. g. >99 % yield and conversion of aniline in very short time and mild conditions). Owing to the magnetic part, the nanoparticles can be easily separated and reused, showing an almost stable activity after 10 cycles.

A review on sustainable iron oxide nanoparticles: syntheses and applications in organic catalysis and environmental remediation

“…In the similar context, Sarno et al prepared core-shell Fe 3 O 4 /Au nanocatalyst and deployed it for the N-alkylation reactions. 146 2.1.3. Sonogashira coupling.…”