The CL emission in the scanning electron microscope from dislocations and subgrain boundaries is studied in MgO crystals having different impurity contents and in Fe doped crystals. It is found that iron acts as a quencher of CL from defects and that there are some differences in the CL spectra obtained from the different crystals. The results are attributed to decoration of dislocations by impurities and other point defects. Variations of spectral distribution caused by irradiation in the electron microscope are also reported.