Semiclassical analysis of jm → j′m′ transitions in rotationally inelastic collisions in cell experiments

Abstract

Recent quantum calculations of rotationally inelastic collisions of NaK (AΣ) with He or Ar in a cell experiment are analyzed using semiclassical approximations valid for large quantum numbers. The results suggest a physical interpretation of jm → j'm' transitions based on the vector model and lead to expressions that explicitly involve the initial and final polar angles of the angular momentum of the target molecule. The relation between the polar angle θ and the azimuthal quantum number m links the semiclassical results for the change in polar angle (θ → θ') to quantum results for an m → m' transition. Analytic formulas are derived that relate the location and width of peaks in the final polar angle distribution (PAD) to the K-dependence of the coefficients d(j, j'), which are proportional to tensor cross sections σ(j → j'). Several special cases are treated that lead to final PADs that are approximately Lorentzian or sinc functions centered at θ' = θ. Another interesting case, "angular momentum reversal," was observed in the calculations for He. This phenomenon, which involves a reversal of the direction of the target's angular momentum, is shown to be associated with oscillatory behavior of the d for certain transitions. Finally, several strategies for obtaining the d coefficients from experimental data are discussed.

The effect of collisions on the rotational angular momentum of diatomic molecules studied using polarized light

“…Examples of other homonuclear as well as heteronuclear diatomic molecules that were used in such studies include I2 [24][25][26], Br2 [27,28], N2 [29], NaLi [30], NaK [31][32][33], NaCs [33], CsF [34], and BaO [40], among others. Theoretical studies of rotationally inelastic collisions have also been carried out [41][42][43][44][45][46][47][48], and good agreement between calculated and measured cross sections was obtained for the ( )…”