Strontium substituted praseodymium manganite Pr 0.7 Sr 0.3 MnO 3 powder was synthesized by a solid state reaction method at 1400 C. Neutron diffraction analysis at room temperature and at 14.5 K shows that our sample belongs to the Pnma space group at both temperatures. At low temperature, the refinement gave 3.368m B for the Mn atoms and 0.273m B for the Pr atom, aligned ferromagnetically along the crystallographic y-axis. Magnetic measurements show that our sample exhibits a paramagnetic-ferromagnetic transition with decreasing temperature. The Curie temperature, T C , is found to be 250 K. Electrical studies show a semiconductor-metal transition at T r = 260 K. This transition temperature is observed in the vicinity of the Curie temperature T C . Magnetotransport properties show a sharp drop in resistivity as a function of the magnetic applied field. Our sample displays a magnetoresistance effect at 8 T of about 80% in the vicinity of the Curie temperature T C . 55 Mn NMR measurements at 4.2 K confirm the metallic behavior at low temperature. The time average resonance frequency indicates that electron hopping between Mn 3+ and Mn 4+ occurs over the whole crystal.