Semiconductor Properties of π‐Extended 2‐(Thiopyran‐4‐ylidene)‐1,3‐benzodithiole (TP‐BT) Analogs
Hiroshi Nishimoto,
Tomofumi Kadoya,
Takeshi Kawase
et al.
Abstract:Despite having an asymmetric structure, 2‐(thiopyran‐4‐ylidene)‐1,3‐benzodithiole (TP‐BT) is a good p‐type semiconductor containing isotropic three‐dimensional (3D) intermolecular interactions. Moreover, its π‐extended analogs can potentially work as organic electronic materials. Herein, a fused‐type π‐extended analog containing an extra benzene ring on the benzodithiole unit, i.e., 2‐(thiopyran‐4‐ylidene)‐1,3‐naphtho[2,3‐d]dithiole (TP‐NT), and three σ‐bonded‐type π‐extended analogs, i.e., phenyl‐, naphthyl‐,… Show more
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