“…As ac lassical type of off-stoichiometric oxygen catalyst, the La 1Àx Sr x BO 3 (LSB;B= Cr,M n, Fe, Co, Ni)p erovskite series have been widely exploited in various catalytic fields, for example, fuel cells, [8][9][10] electrocatalysis, [11][12][13][14][15] and chemical sensors [16][17][18] , owing to their structural tunability,r apid ion mobility,a nd remarkable V O formation ability.R ecently,s omeL SB perovskite oxidesw ith aS rd oping content of 0.4, such as La 0.6 Sr 0.4 MnO 3 [19] and La 0.6 Sr 0.4 FeO 3 , [20] were proposed as promising alternative catalysts for thermochemical water-splitting applications, with impressive V O formation ands olar H 2 production performances at lowt emperature. As such, the thermochemical catalytic properties of LSB-type catalysts are strongly relatedt ot heir materialc ompositions.…”