Sensitive voltammetric method for the determination of naproxen at the surface of carbon nanofiber/gold/polyaniline nanocomposite modified carbon ionic liquid electrode

Afzali, Moslem; Jahromi, Zahra; Nekooie, Reyhaneh

doi:10.1016/j.microc.2018.10.046

Cited by 35 publications

(28 citation statements)

References 45 publications

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“…15,16 Electrochemical sensors prepared by modifying various electrodes to create selective regions specific to analytes are very useful for clinical, environmental, and biomechanical analysis. 17 Naproxen has been determined voltammetrically using various electrodes, including mercury, 18 platinum, 19,20 boron-doped diamond, 2,21 gold, 22 glassy carbon, 23 carbon nanofiber, 24 graphite, 25,26 multiwalled carbon nanotubes/glassy carbon 27,28 graphene oxide 29 and nanomaterial modified carbon paste [30][31][32] electrodes.…”

Section: Introductionmentioning

confidence: 99%

Determination of naproxen by using differential pulse voltammetry with poly (aniline-2-sulfonic acid) modified boron doped diamond electrode

Güngör

2022

Maced. J. Chem. Chem. Eng.

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In this study, an electrochemical sensor based on a boron doped diamond electrode (BDDE) was developed for the determination of naproxen (NAP) using a poly(aniline-2-sulfonic acid)/boron doped diamond electrode, p(A2SA/BDDE). Polymerization of A2SA was conducted in a water/acetonitrile (1:1) mixture containing 0.1 M sodium perchlorate (NaClO4) on bare BDDE and the electrochemical properties studied by cyclic voltammetry in ferricyanide/KNO3 solution. The prepared p(A2SA/BDDE) was used for detection of NAP. Effects of parameters such as monomer type and concentration, the number of cycles, and scan rate were investigated using differential pulse voltammetry (DPV) in phosphate buffer containing 0.75 mM NAP. The effect of electrolyte type and pH on DPV responses to NAP were also studied. The oxidative current peak stem from NAP concentration observed at 1.1 V potential. A linear calibration curve was obtained in the range of 0.05–1.00 mM NAP concentration. Correlation coefficient (R2), detection limit, and quantification limit were calculated as 0.9944, 0.0328 mM, and 0.1093 mM, respectively. In conclusion, it may be claimed that the modified electrode constructed in this work can be used successfully as a naproxen-selective membrane due to its ease of preparation, high R2 value, and good reproducibility.

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Section: Introductionmentioning

confidence: 99%

Determination of naproxen by using differential pulse voltammetry with poly (aniline-2-sulfonic acid) modified boron doped diamond electrode

Güngör

2022

Maced. J. Chem. Chem. Eng.

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“…Recently, carbon ionic liquid electrode (CILE) has been used extensively in the field of electrochemistry with the merits including reasonably priced, easy preparation, high conductivity, and wide electrochemical windows. CILE can be constructed by changing the organic binder with high ionic conductive ionic liquids, which indicate superb electrochemical performances than the classical working electrodes [36–40] …”

Section: Introductionmentioning

confidence: 99%

A Carbon Ionic Liquid Paste Sensor Modified with Lanthanum Nanorods /MWCNTs/Nafion Hybrid Composite for Carbamazepine Screening in Biological and Pharmaceutical Media

et al. 2021

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In this original paper, a new electrochemical sensor for carbamazepine (CBZ) was developed. First, lanthanum nanorods (LaNRs) were synthesized by a simple microemulsion method. Then, a nanocomposite consist of lanthanum nanorods, multiwalled carbon nanotubes (MWCNTs), and nafion (LaNRs/MWCNTs/Nafion) was prepared and deposited at the surface of the carbon ionic liquid paste electrode (CILPE). X‐ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersion spectroscopy (EDS), and scanning electron microscopy (SEM) were used to characterize the structure of synthesized LaNRs and the surface morphology of the modified electrode. Also, electrochemical methods such as cyclic voltammetry (CV), square wave voltammetry (SWV), and electrochemical impedance spectroscopy (EIS) were utilized to investigate the performance of the proposed electrode. Under the optimal conditions, a linear relationship of the electrical signal versus the concentration of CBZ was obtained in the range from 0.06 μM to 20 μM with a detection limit (LOD) of 0.006 μM and quantification limit (LOQ) of 0.02 μM. Eventually, the fabricated sensor was satisfactorily applied for rapid and accurate determination of CBZ in real samples.

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“…Many studies reported in the literature have proposed several devices and techniques for the detection of naproxen. Some of these techniques are based on chromatographic separation and spectrophotometric detection mechanisms [8][9][10][11], while others are based on electrochemical mechanisms [12][13][14][15][16].…”

Section: Introductionmentioning

confidence: 99%

“…The sensor was fabricated using bismuth vanadate film modified with copper oxide, forming the nanocomposite BiVO 4 /CuO. BiVO 4 , when present in monoclinic crystalline structure, is an n-type semiconductor that presents a suitable band gap of 2.4 eV for the generation of photocurrent under visible light irradiation [12]. In general, the application of BiVO 4 in electrochemical devices involves the photo excitation of electrons from the valence band (VB) to the conduction band (CB).…”

Section: Introductionmentioning

confidence: 99%

Using Bismuth Vanadate/Copper Oxide Nanocomposite as Photoelectrochemical Sensor for Naproxen Determination in Sewage

et al. 2020

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Conventional sewage treatment plants are not usually designed to remove emerging contaminants, and this shortcoming leads to the discharge of pharmaceuticals, among other emerging pollutants, into the environment. The present work reports the development of BiVO4/CuO‐based photoelectrochemical sensor for the determination of naproxen in sewage samples. Morphological characterizations were carried out by X‐ray diffraction and Scanning electron microscopy. The band gap energy of the nanocomposite material was calculated by Tauc plots using the data obtained from diffuse reflectance spectroscopy analysis. The sensor presented analytical signal during the photocurrent generation simultaneously with the oxidation of naproxen on the working electrode. The sensor responses were found to be proportional to the increase in naproxen concentration in the linear range of 5 nmol L−1 to 480 nmol L−1, R2=0.996, with a limit of detection of 5 nmol L−1. The presence of naproxen in sewage samples was successfully determined with recovery percentages above 95 %.

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Sensitive voltammetric method for the determination of naproxen at the surface of carbon nanofiber/gold/polyaniline nanocomposite modified carbon ionic liquid electrode

Cited by 35 publications

References 45 publications

Determination of naproxen by using differential pulse voltammetry with poly (aniline-2-sulfonic acid) modified boron doped diamond electrode

Determination of naproxen by using differential pulse voltammetry with poly (aniline-2-sulfonic acid) modified boron doped diamond electrode

A Carbon Ionic Liquid Paste Sensor Modified with Lanthanum Nanorods /MWCNTs/Nafion Hybrid Composite for Carbamazepine Screening in Biological and Pharmaceutical Media

Using Bismuth Vanadate/Copper Oxide Nanocomposite as Photoelectrochemical Sensor for Naproxen Determination in Sewage

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