When a single emitter is excited by two phase-coherent pulses with a time delay, each of the pulses can lead to the emission of a photon pair, thus creating a "time-bin entangled" state. Double pair emission can be avoided by initially preparing the emitter in a metastable state. We show how photons from separate emissions can be made indistinguishable, permitting their use for multi-photon interference. Possible realizations are discussed. The method might also allow the direct creation of n-photon entangled states (n > 2).The development of convenient sources of entangled photons is an important task in quantum information [1]. Entangled photons have been used to realize fundamental quantum information procedures such as quantum key distribution [2,3,4], quantum teleportation [5,6,7] and entanglement swapping [8]. The latter task is an essential element of quantum repeaters [9], which would allow the distribution of entanglement over very long distances. Recently entangled photons were also used to implement simple quantum logic gates [10].The standard source of entangled photons at the moment is parametric down-conversion [1], which is based on the conversion of pump photons into pairs of photons inside a non-linear optical crystal. An important drawback of downconversion sources is the fact that they cannot be made to produce exactly one pair of photons. They always generate a statistical distribution of pairs. If the probability to create a single pair with a given pump pulse is p, then there is a probability of order p 2 to create two or more pairs with the same pump pulse. This feature of down-conversion sources leads to limitations on their performance for various quantum information procedures, such as teleportation [11], quantum cryptography [12] and entanglement purification [13]. It would thus be very desirable to have a convenient source of individual pairs of entangled photons, where one can be sure that no more than one pair is emitted.A natural approach towards realizing such sources is to use photonic cascades from atoms or semiconductor quantum dots. Atomic cascades were used to produce polarizationentangled photons in the first tests of Bell inequalities [14]. Quantum dot sources are attractive because they are compact and can be fairly easily integrated into semiconductor microcavity structures to enhance the probability for emission of the photons into a well-defined mode. These features have recently been demonstrated for single-photon sources [15]. There is a recent proposal for a quantum dot source of single pairs of polarization entangled photons [16], based on the biexciton-exciton cascade. However, the generation of polarization entanglement with this source requires the two intermediate exciton states with different spin to be exactly degenerate, which is not the case for currently available quantum dots, due to their lack of exact rotational symmetry around the direction of growth. In consequence, current quantum dots can emit polarization-correlated, but not polarizationentangled, p...