Additional Information:• NOTICE: this is the author's version of a work that was accepted for publication in the International Journal of Hydrogen Energy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was sub- Regardless of the mixture stoichiometry, the hydrogen substitution to methane leads to a transition from a regime in which the vortex only wrinkles the flame front (x H2 < 0.2) to a * Corresponding author. Phone: +39 0817622673; Fax: +39 0817622915; E-mail address: valeria.disarli@irc.cnr.it 3 more vigorous regime in which the interaction almost results in the separation of small flame pockets from the main front (x H2 > 0.2). This transition was characterised in terms of time histories of flame surface area and burning rate.