Effect of weak carbide formers, Mo, Mn and Si, on intergranular corrosion (IGC) of low-Cr ferritic stainless steel is analyzed after IGC test using TEM and three dimensional atom probe. The co-addition of Mo, Mn and Si to low-Cr ferritic stainless steel effectively prevents IGC by forming along grain boundaries CMn 4 MoSi intermetallic compounds, which act not only as carbon trap sites but also as diffusion barrier against solute Cr diffusion toward grain boundaries. The low solubility of Cr in the CMn 4 The low-chromium (Cr) ferritic stainless steels (FSSs) are widely used as an economical structural material in moderate corrosive environments because they have high strength and good corrosion resistance. The low-Cr FSSs contain Cr content in a range of 11 to 13 wt% and they are used for automotive exhaust system, chemical processing equipment, furnace parts, heat exchangers, recuperates, oil burner parts and storage vessels.1,2 Welding is an inevitable manufacturing process to make the structural components with low-Cr FSS. Since fusion welding such as gas metal arc welding (GMAW) is a common practice for low-Cr FSS, during service, it often results in a serious industrial problem of sensitization or intergranular corrosion (IGC).
2-4Sensitization occurs quite easily in FSS, which has body centred cubic (BCC) structure, because of its low solubility of interstitial elements of carbon (C) and nitrogen (N).5 In FSS, sensitization may occur as fast as less than 0.01 s because of high diffusivity of C and N in BCC structure.6 Therefore, prevention of sensitization of low-Cr FSS requires careful alloy design with a clear understanding on the IGC mechanism.IGC of stainless steel is known to occur due to electrochemical potential difference between the matrix and Cr depleted zone in the vicinity of grain boundary area. According to the conventional IGC mechanism, 6-8 Cr depletion and consequent IGC are induced by formation of Cr-carbide and/or Cr-carbonitride along grain boundaries. Based on the conventional IGC mechanism, the general commercial recommendation to prevent IGC of stainless steel is reduction in the content of C and N, and addition of strong carbide former as a stabilizer such as titanium (Ti) and niobium (Nb). For austenitic stainless steels, it is recommended to reduce the C content to less than 0.03 wt%, wheareas for ferritic stainless steels, to reduce the total amount of C and N less than 0.01 wt%. 6,8 The amount of stabilizer to prevent IGC varies depending on the alloy composition and welding process. To recommend the proper amount of stabilizer, the stabilization ratio (SR) is commonly used, where SR is defined as the ratio of the total amount of Ti and Nb to total amount of C and N. For low-Cr FSS, the technical standards of ASM and ASTM recommend various amount of stabilizer equivalent to SR values of 5 to 6. 8,9 Niekerk et al. have suggested SR value more than 6 with specific heat input level, 10 whereas Fritz and Franson have recommended it be more than 8. However, most IGC tests on 409 FSS...