Separation of phenols and ketones from bio-oil produced from ethanolysis of wheat stalk

Yang, Hua; Zhao, Wei; Norinaga, Koyo; Fang, Jun Ji; Wang, Yugao; Zong, Zhi Min; Wei, Xian Yong

doi:10.1016/j.seppur.2015.03.032

Cited by 32 publications

(16 citation statements)

References 29 publications

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“…These compounds are widely employed in the production of phenolic resins [31]. They also have antioxidant and antimicrobial properties that inhibit the proliferation of microorganisms, corrosion and deposits when added to diesel fuel formulations and/or biodiesel for use in engines (use of biomass-derived compounds) [32,33].…”

Section: Page 3 Ofmentioning

confidence: 99%

Bio-Oil Production by Thermal Cracking in the Presence of Hydrogen

Veses¹,

Shah²

2015

J Fundam Renewable Energy Appl

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This paper describes the bio-oil production process of a mixture of agricultural wastes: discarded soybean frying oil, coffee and sawdust, by pyrolysis and thermal cracking in the presence of hydrogen. The fractions obtained in the pyrolysis and/or cracking processes were divided into a light fraction and a heavy one. All the fractions were analyzed by comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry detection (GC×GC/ TOFMS). The characteristics of the fractions obtained in from the cracking process in the presence of hydrogen were similar to those of petroleum-based naphtha, while the fractions obtained by pyrolysis contained significant quantities of compounds such as furanmethanol, hexanol, and benzofuran, whose commercial value is high.

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Section: Page 3 Ofmentioning

confidence: 99%

Bio-Oil Production by Thermal Cracking in the Presence of Hydrogen

Veses¹,

Shah²

2015

J Fundam Renewable Energy Appl

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“…Therefore, ion‐exchange chromatography could be attempted to isolate KGA and PYR. Adsorption chromatography is commonly used to separate low‐cost chemical materials, that is, saturates, paraffins and mono‐aromatics as a traditional method . Both the polarity difference of substances and adsorbents play a crucial role in adsorption chromatography.…”

Section: Introductionmentioning

confidence: 99%

“…Adsorption chromatography is commonly used to separate low-cost chemical materials, that is, saturates, paraffins and mono-aromatics as a traditional method. [21][22][23] Both the polarity difference of substances and adsorbents play a crucial role in adsorption chromatography. The polarity of KGA is higher than the polarity of PYR.…”

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confidence: 99%

Separation of α‐ketoglutaric acid and pyruvic acid from the culture broth of Yarrowia lipolytica WSH‐Z06 by chromatographic methods

Peng

Zeng

et al. 2018

Biotechnology Progress

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Both α‐ketoglutaric acid (KGA) and pyruvic acid (PYR) are important keto acids. Efficient co‐production of KGA and PYR has been achieved in our previous work, and could significantly decrease the cost of fermentation production. KGA and PYR have similar physical and chemical properties. Hence, finding a way to separate the two keto acids efficiently has become a key challenge. In this study, different chromatographic methods have been investigated, including ion‐exchange chromatography, aluminum oxide chromatography and silica gel chromatography. The results show that the two keto acids can be well separated with silica gel chromatography, whereas ion‐exchange chromatography and aluminum oxide chromatography could not separate them. Using the pretreated fermentation broth of Yarrowia lipolytica WSH‐Z06, the purity and yield of KGA/PYR reached 98.7%/99.1% and 86.7%/70.9%, respectively, with an optimized silica gel chromatography‐based procedure. This study provides an efficient method for separating KGA and PYR from fermentation broth, which might be applied on an industrial scale and significantly decrease the cost of biotechnological production of keto acids. © 2018 American Institute of Chemical Engineers Biotechnol. Prog., 34:1370–1379, 2018

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“…Bio-Oil, a liquid product from thermal conversion of biomass has been paid attention to provide fuels and chemicals [1]. The rising demand for energy, chemicals, and materials from sustainable resources poses challenging efforts.…”

Section: Introductionmentioning

confidence: 99%

“…These facts lead biodiesel to enhance more complete combustion and less emission of particulate matter [26,27]. Recently, catalytic pyrolysis has aroused a great interest for the advantages of operating at atmospheric pressure and the lack of need for hydrogen [28,29]. Recently, increasing attention has been paid to the recovery of chemicals from bio-oil, providing chemicals compared to fuels could make recovery of even small concentrations viable.…”

Section: Introductionmentioning

confidence: 99%

A Comparative Study and Analysis of Two Types of Bio-Oil Samples Obtained from Freshwater Algae and Microbial Treated Algae

Shah¹

2016

Mod Chem Appl

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Pyrolysis experiments of two types of algal biomass (Spirogyra) freshwater Algae (FWA) and microbial treated algae (MTA) were carried out in an electrically heated stainless steel reactor to determine the effects of pyrolysis temperature, pyrolysis product yields and bio-oil properties. After pyrolysis two types of bio-oil were produced, freshwater algae bio-oil (FWAB) and microbial treated algae bio-oil (MTAB). Gas chromatography/mass spectrometry (GC-MS) analysis and Fourier transform infrared spectroscopy (FTIR) has been done of both types of bio-oil samples and also a comparison is shown between these two samples and explained it with the help of graphs and tables. The bio-oil was obtained from pyrolysis in which temperature of the system was kept 25°C and then increased up to 650°C time by time. After pyrolysis the obtained bio-oil was introduced to distillation and then analyzed by GC-MS technique and FTIR, which show different peaks and results of different compounds and functional groups present in both bio-oil samples and a noticeable difference is shown between these two bio-oil samples on the basis of hydrocarbons as well as other compounds.

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Separation of phenols and ketones from bio-oil produced from ethanolysis of wheat stalk

Cited by 32 publications

References 29 publications

Bio-Oil Production by Thermal Cracking in the Presence of Hydrogen

Bio-Oil Production by Thermal Cracking in the Presence of Hydrogen

Separation of α‐ketoglutaric acid and pyruvic acid from the culture broth of Yarrowia lipolytica WSH‐Z06 by chromatographic methods

A Comparative Study and Analysis of Two Types of Bio-Oil Samples Obtained from Freshwater Algae and Microbial Treated Algae

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