Separation of thorium from uranium and rare‐earth elements by solvent extraction with tri ‐ n ‐ butyl phosphate ‐ xylene

Abstract

A study is made of three processes for the separation of thorium from uranium and rare‐earth elements in crude thorium nitrate solutions prepared by breakdown of monazite sand. Uranium may be separated from thorium and rare‐earth elements in a preliminary extraction with 5% or 40% v/v tri‐n‐butyl phosphate (TBP) in xylene and the thorium separated from the rare‐earth elements in a subsequent extraction with 40% v/v TBP in xylene. Alternatively thorium and uranium may be extracted simultaneously from the solutions with 40% TBP in xylene and the thorium preferentially backwashed from the loaded solvent with dilute HNO3. The present work indicates that processes in which uranium only is extracted in the first operation will be the most flexible and the simplest to operate. The partition coefficients for zirconium, which occurs as an additional contaminant in solutions prepared from thorite ores, have also been determined by batch extraction with 5% and 40% TBP in xylene and the data confirmed in a continuous countercurrent system.

Separation of Thorium from Zirconium Carbide Waste by Liquid–Liquid Extraction Using Tri-n-octylamine Solvent after Selective Acid Leaching

“…The extraction of uranium by TBP is much stronger than that of thorium and REEs. Menzies and Rigby used 5% (v/v) TBP in xylene to extract uranium and separate it from thorium and REEs from the nitrate solution . The separation of thorium, uranium, and REEs was investigated in a series of acidic solutions with Cyanex 923 .…”

“…Menzies and Rigby used 5% (v/v) TBP in xylene to extract uranium and separate it from thorium and REEs from the nitrate solution. 48 The separation of thorium, uranium, and REEs was investigated in a series of acidic solutions with Cyanex 923. 49 It has been reported that Cyanex 272 can strongly extract thorium and uranium even in strong HNO 3 solutions, up to 4 M. 50 Uranium and thorium can also be extracted by TBP from the HCl solution.…”