Sequence-Defined Polypeptide−Polymer Conjugates Utilizing Reversible Addition Fragmentation Transfer Radical Polymerization

Cate, Mattijs G. J. Ten; Rettig, Hartmut; Bernhardt, Katrina T.; Börner, Hans G.

doi:10.1021/ma0519415

Cited by 126 publications

(83 citation statements)

References 40 publications

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“…438,439 Similar strategies have been employed to synthesize peptides bearing initiators for controlled polymerization in solution via ATRP, 14,440–442 as well as RAFT. 443 Solid phase strategies have also been utilized for the preparation of conjugated polymer-peptide hybrids, 444 various PEG-peptide block copolymers, 445,446 dendrimer hybrids 89,447 among many other examples. 406,413 …”

Section: Functionalization Of Biological Systemsmentioning

confidence: 99%

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

et al. 2009

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Section: Functionalization Of Biological Systemsmentioning

confidence: 99%

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

et al. 2009

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“…Peptide BA [489] 25 Polyisobutylene (127) MMA [296] St 95 Poly(3-hexylthiophene) (99) 303 [264] Graft 115 Chitosan AA [487] 115 Silica (amine modified) MA [490] 25 Silicon wafer (amine modified) MMA [179] 103 * Silicon wafer (amine modified) NIPAM [273] A Substrate used in forming macro-RAFT agent. B Monomer polymerized in presence of Block A macro-RAFT agent.…”

Section: Block Copolymersmentioning

confidence: 99%

Living Radical Polymerization by the RAFT Process - A Second Update

Moad¹,

Rizzardo²,

Thang³

2009

Aust. J. Chem.

906

720

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This paper provides a second update to the review of reversible deactivation radical polymerization achieved with thiocarbonylthio compounds (ZC(=S)SR) by a mechanism of reversible addition-fragmentation chain transfer (RAFT) that was published in June 2005 (Aust. J. Chem. 2005, 58, 379-410). The first update was published in November 2006 (Aust. J. Chem. 2006, 59, 669-692). This review cites over 500 papers that appeared during the period mid-2006 to mid-2009 covering various aspects of RAFT polymerization ranging from reagent synthesis and properties, kinetics and mechanism of polymerization, novel polymer syntheses and a diverse range of applications. Significant developments have occurred, particularly in the areas of novel RAFT agents, techniques for end-group removal and transformation, the production of micro/nanoparticles and modified surfaces, and biopolymer conjugates both for therapeutic and diagnostic applications.

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“…Controlled emulsion polymerization was achieved, as evidenced by linear first-order kinetics and narrow M w /M n ¼ 1.2-1. 4 [ Fig. 9(b)].…”

Section: Seeded Emulsion Polymerization In the Presence Of Controlledmentioning

confidence: 99%

Recent advances in controlled/living radical polymerization in emulsion and dispersion

2008

J. Polym. Sci. A Polym. Chem.

142

126

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Effective ways to conduct controlled/living radical polymerization (CRP) in emulsion systems are necessary for commercial latex production without significant modification of current industrial facilities. Conducting CRP in emulsion media is more complicated and more challenging than its application in homogeneous bulk. These challenges come from the intrinsic kinetics of emulsion polymerization. They include mass transport, slow chain growth mechanism, and exit of short radicals from polymeric particles. This review describes the recent developments of CRP in heterogeneous dispersion, including miniemulsion, microemulsion, dispersion, and especially emulsion. Various approaches for conducting emulsion CRP are detailed, including controlled seeded emulsion polymerization, nanoprecipitation, use of short oligomers as macroinitiators for in situ block copolymerization, and RAFT-mediated selfassembly. In addition many remaining challenges of the current methods barring wide spread industrial application of emulsion CRP are also suggested.

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Sequence-Defined Polypeptide−Polymer Conjugates Utilizing Reversible Addition Fragmentation Transfer Radical Polymerization

Cited by 126 publications

References 40 publications

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

Living Radical Polymerization by the RAFT Process - A Second Update

Recent advances in controlled/living radical polymerization in emulsion and dispersion

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