Serendipitous synthesis of 4-thioxochromen-2-one derivatives through the one-pot three-component reaction of primary amines, carbon disulfide, and 4-chlorocoumarin-3-carbaldehyde

Aghaalizadeh, Tooran; Nasiri, Farough

doi:10.1080/17415993.2017.1337769

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Reactions With Electrophiles1

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Cited by 4 publications

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“…Aghaalizadeh and Nasiri 9b used 4-chlorocoumarin-3-carbaldehyde 7.5 in the synthesis of sulfur-containing coumarins 7.6 (Scheme 7 ). The products 7.6 were obtained in good to excellent yields within 30 minutes at room temperature.…”

Section: Reactions With Electrophilesmentioning

confidence: 99%

A Decade of Advances of CS2/Amines in Three-Component Reactions

Wang

et al. 2022

Synthesis

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Carbon disulfide (CS2) and amines are widely used in three-component reactions. Commonly, dithiocarbamic acids will be generated. As intermediates, dithiocarbamic acids are able to react with electrophiles, or nucleophiles. The goal of this review is to present an overview of CS2/amines in organic synthesis. It focuses on reactions with alkenes, alkynes, I2, arynes, allenes, quinones, vinyl chlorides, aryl halides, aryl boronic acids, 2-iodoanilines, 2-aminophenols, hypervalent iodines, epoxide, or maleic anhydride.

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Section: Reactions With Electrophilesmentioning

confidence: 99%