We study the Bloch and the little Bloch spaces of harmonic functions on the real hyperbolic ball. We show that the Bergman projections from $$L^\infty ({\mathbb {B}})$$
L
∞
(
B
)
to $${\mathcal {B}}$$
B
, and from $$C_0({\mathbb {B}})$$
C
0
(
B
)
to $${\mathcal {B}}_0$$
B
0
are onto. We verify that the dual space of the hyperbolic harmonic Bergman space $${\mathcal {B}}^1_\alpha $$
B
α
1
is $${\mathcal {B}}$$
B
and its predual is $${\mathcal {B}}_0$$
B
0
. Finally, we obtain atomic decompositions of Bloch functions as series of Bergman reproducing kernels.