Let Ω i , Ω o be bounded open connected subsets of R n that contain the origin. Let Ω(𝜖) ≡ Ω o ∖𝜖Ω i for small 𝜖 > 0. Then, we consider a linear transmission problem for the Helmholtz equation in the pair of domains 𝜖Ω i and Ω(𝜖) with Neumann boundary conditions on 𝜕Ω o . Under appropriate conditions on the wave numbers in 𝜖Ω i and Ω(𝜖) and on the parameters involved in the transmission conditions on 𝜖𝜕Ω i , the transmission problem has a unique solution (u i (𝜖, •), u o (𝜖, •)) for small values of 𝜖 > 0. Here, u i (𝜖, •) and u o (𝜖, •) solve the Helmholtz equation in 𝜖Ω i and Ω(𝜖), respectively. Then, we prove that ifx ∈ Ω o ∖ {0}, then u o (𝜖, x) can be expanded into a convergent power expansion of 𝜖, 𝜅 n 𝜖 log 𝜖, 𝛿 2,n log −1 𝜖 for 𝜖 small enough. Here, 𝜅 n = 1 if n is even and 𝜅 n = 0 if n is odd, and 𝛿 2, 2 ≡ 1 and 𝛿 2, n ≡ 0 if n ≥ 3.