SummaryThe Voice over Long‐Term Evolution (VoLTE) cell capacity notably has an influence on Call Admission Control (CAC) in Long‐Term Evolution (LTE) network. In literature, many techniques have been studied to estimate the LTE cell capacity, but most of them are throughput‐based physical layer (PHY layer) estimate. These estimates do not consider delay requirement, transmission loss, and protocol overhead. In this paper, we have proposed novel analytical models for estimating the VoLTE cell capacity in terms of number of users by considering available physical resource blocks (PRBs) in each bandwidth, voice traffic‐based characteristics such as voice activity factor (VAF), silent insertion descriptor (SID), and radio‐specific techniques such as packet bundling and transmission time interval (TTI) bundling. Our developed analytical models are then used to investigate the effect of modulation and coding scheme (MCS) and Adaptive Multi‐RateWideband (AMR‐WB) voice codec on VoLTE cell capacity. Results show that higher order modulation scheme with lower bit voice codec accommodates maximum number of VoLTE users. Further, the impact of VAF, SID, packet bundling, and TTI bundling on VoLTE cell capacity is investigated in different radio conditions. Finally, using our proposed model, the effect of hybrid automatic repeat request (HARQ) retransmission on VoLTE cell capacity is investigated.