“…Controlled/living radical polymerization (CLRP or CRP) or reversible deactivation radical polymerization (RDRP) [11] is a series of useful techniques for the synthesis of tailormade polymers with applications in many fields such as electronics, adhesives, coatings, pharmaceutics, chromatography, biomaterials, etc. [12][13][14][15][16][17][18][19][20][21] These experimental techniques can be conducted as homogenous or heterogeneous processes; for instance, in bulk, solution or dispersion, using organic, ionic liquids, or "green" solvents, such as supercritical carbon dioxide (scCO2). [22][23][24][25][26][27][28][29] The most studied CLRP systems include atom transfer radical polymerization (ATRP), [30] reversible addition-fragmentation chain transfer (RAFT) polymerization, [31][32][33] and nitroxide-mediated radical polymerization (NMRP), [34,35] although other CLRP techniques such as…”