A study on low-refractive-index SiO 2 antireflective (AR) coatings by a sol-gel method is reported. Variations in the properties of the coatings are related to the molar ratios of ammonia to deionized water being changed in the process of preparing the sols. From the performance test results, the optimal ratio of the reactants necessary to prepare low-refractive-index SiO 2 AR coatings is determined. Of all the SiO 2 AR coatings, the lowest recorded refractive index is 1.16 at a wavelength of 700 nm. The largest water contact angle is 121.2°, and the peak transmittance is 99.95% at a wavelength of 908 nm. Furthermore, the sol used to deposit the film with the lowest refractive index is stable because of the narrow size distribution of its constituent particles.OCIS The sol-gel method is a widely used technique in the preparation of materials with different morphologies. Thin films, powders, fibers, and other morphologies can be prepared by altering the processing conditions. The sol-gel method has been adopted widely and has seen rigorous development in the field of thin films. Sokolova et al. were the first to apply sol-gel coatings in the domain of highpower laser devices in 1967 [1] . After that, sol-gel chemical coatings developed quickly and became an important feature of high-power laser devices. SiO 2 antireflective (AR) coatings prepared by the sol-gel method have good optical properties and high laser-induced damage thresholds. There are many optical elements that require SiO 2 AR coatings in large high-power laser devices around the world [2] , such as the National Ignition Facility in the USA [3] , the Laser MégaJoules in France [4,5] , and the "Shenguang" systems in China [6][7][8] . Compared with films of high-refractive-index media made by physical vapor deposition, the refractive index of SiO 2 AR coatings made by the sol-gel method are not only low but also controllable [9,10] . According to the theory of optical film system design, double-layer, widebandwidth AR coatings can be achieved by depositing a high-refractive-index layer onto a substrate, followed by the deposition of a low-refractive-index thin film. It can effectively improve the light transmission efficiency of optical elements. In this Letter, SiO 2 AR coatings with low refractive indices were obtained by adjusting the molar ratios of ammonia and deionized water when the sols were prepared. The particle size distributions and viscosities of the sols were measured; sols with a narrow particle size distribution are stable and have a long lifetime. The lowest refractive index recorded was 1.16 at a 700 nm wavelength; the optical properties and hydrophobic performances of this coating are excellent. Thus, the results could be beneficial in the development of double-layer, wide-bandwidth AR coatings.The SiO 2 sols were prepared by the Stöber method using base catalysis of ammonia [11] . The solutions, catalyzed with ammonia ðNH 3 Þ, were mixed with the reactants tetraethoxysilane (TEOS), deionized water ðH 2 OÞ, and ethanol ðC 2 H 5 OHÞ....