Shaggy-like Ru-clusters decorated core-shell metal-organic framework-derived CoOx@NPC as high-efficiency catalyst for NaBH4 hydrolysis

Electrocatalytic water oxidation performance in an extended porous organic framework with a covalent alliance of distinct Ru sites

“…on Ru clusters in core–shell metal–organic frameworks. 27 It is also important to mention that the polymer network structure has been grown with interlocked metal coordinated monomers that provide Ru-based isolated catalyst centers rather than Ru or RuO 2 nanoparticles (as experimentally observed from the PXRD and TEM images). These isolated Ru catalyst centers are tightly wrapped with dense polymer units resulting in minimum exposure on the external surface to acquire some specific shape.…”

“…However, we speculate that this may be due to the ultra low loading of Ru species with a much sparser dispersion inside the POP unit framework, which is consistent with previous work by Yang et al on Ru clusters in core-shell metal-organic frameworks. 27 It is also important to mention that the polymer network struc-Fig. 2 (a) 13 C-CP solid state MAS NMR spectrum, (b) N 2 -adsorption/desorption isotherms, and (c) pore-size distribution as measured by the NLDFT method of Ru@Bpy-POP.…”

Constructing Ru Clusters Decorated Co3b-Cop Heterostructures as a Highly Active and Reusable Catalyst for H2 Generation by Catalyzing Nabh4 Hydrolysis

“…5d) and many previously reported catalysts but not the lowest (Table S3). The low activation energy implies that the Ru 6.3 /Co 3 B-CoP catalyst has a lower energy barrier, thereby has a faster reaction kinetics during the reaction process [55].…”