2023
DOI: 10.1002/ange.202309985
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Shape‐Memory Effect Enabled by Ligand Substitution and CO2 Affinity in a Flexible SIFSIX Coordination Network

Bai‐Qiao Song,
Mohana Shivanna,
Mei‐Yan Gao
et al.

Abstract: We report that linker ligand substitution involving just one atom induces a shape‐memory effect in a flexible coordination network. Specifically, whereas SIFSIX‐23‐Cu,[Cu(SiF6)(L)2]n, (L = 1,4‐bis(1‐imidazolyl)benzene, SiF62‐ = SIFSIX) has been previously reported to exhibit reversible switching between closed and open phases, the activated phase of SIFSIX‐23‐CuN, [Cu(SiF6)(LN)2]n (LN = 2,5‐bis(1‐imidazolyl)pyridine), transformed to a kinetically stable porous phase with strong affinity for CO2. As‐synthesized… Show more

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