Shape-selective synthesis of 2-acetylnaphthalene via naphthalene acylation with acetic anhydride over large pore zeolites

Červený, Libor; Mikulcová, Kateřina; Čejka, Jiřı́

doi:10.1016/s0926-860x(01)00743-8

Cited by 54 publications

(21 citation statements)

References 12 publications

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“…The liquid-phase acylation of naphthalene with acetic anhydride was investigated [28] using the large-pore zeolites faujasite, mordenite and Beta over the temperature range 100 to 140 • C, and using trans-decalin as the solvent. Both mordenite and faujasite were rapidly deactivated, in contrast to zeolite Beta.…”

Section: Methodsmentioning

confidence: 99%

Acylation of Aromatics

Kouwenhoven

Bekkum

2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction Zeolite‐Catalyzed Acylation of Aromatics Acylation of Alkylbenzenes Acylation of Naphthalene Acylation of Aromatic Ethers Acylation of Phenols and Fries Rearrangement Ring Closure to Coumarin Derivatives Acylation of Heteroarenes Ordered Mesoporous Materials as Catalysts in Aromatics Acylation Sulfated Zirconium Oxide Catalysts Heteropolyacid Catalysts Activated Clays Nafion ® ‐Type Materials Conclusions

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Section: Methodsmentioning

confidence: 99%

Acylation of Aromatics

Kouwenhoven

Bekkum

2008

Handbook of Heterogeneous Catalysis

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“…Moreover, formation of stable complexes with Lewis acids leads to their destruction when removing the products by water. From these reasons, zeolites [74][75][76][77][78] and mesoporous catalysts [34,79] offer many advantages like high activities, shapeselectivity and last but not least environmental tolerance [35].…”

Section: Acylation Reactionsmentioning

confidence: 99%

Recent Advances in Catalysis Over Mesoporous Molecular Sieves

2009

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This overview covers the recent achievements in the application of mesoporous molecular sieves as catalysts and catalyst supports. Main structural and textural features are outlined in relation to the novel synthesis approaches of mesoporous molecular sieves and understanding of their properties. For application of mesoporous molecular sieves as catalysts different ways of introduction of active sites on their surfaces are provided. The main part describes selected catalytic reactions catalyzed by mesoporous molecular sieves focused on very recent papers. The examples include metathesis, acylation reactions, C-C coupling reactions of Heck and Suzuki types, basecatalyzed reactions (Knoevenagel and Michael additions, Claisen-Schmidt condensation, Tischenko reaction) and last but not least immobilization of organometallic complexes for different catalytic applications including chiral catalysts.

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“…Zeolite SSZ-33 was successfully tested in alkylation reactions of aromatic hydrocarbons such as benzene, toluene and p-xylene, in disproportionation of toluene and xylene [41,43] and as a catalyst for synthesis of fine chemicals in acylation reactions [44]. Recently, the catalytic application and FTIR investigation of SSZ-33 zeolite after isomorphous substitution was published [45].…”

Section: Introductionmentioning

confidence: 99%