This paper introduces an alternative method for determining the shear strength parameters of concrete materials, specifically the rectangular section splitting method, to ascertain the shear strength parameters of concrete materials. Based on the Mohr–Coulomb failure criterion, formulas for calculating the cohesion (c) and the angle of internal friction (φ) of concrete materials are derived. Numerical simulation is employed to fit and solve for the coefficients involved in the formulas. Subsequently, the concrete rectangular section splitting method and direct shear tests are utilized to verify the derived formulas. The results indicate that there is a certain feasibility to the shear strength parameters obtained for concrete materials through the rectangular section splitting method. The cohesion (c) differs by approximately 3.65%, and the angle of internal friction (φ) differs by about 6.94% when compared to the shear strength parameters obtained through direct shear tests. This suggests that the rectangular section splitting method provides a viable approach for determining the shear strength parameters of concrete materials.