Let G be a locally compact group. We shall study the Banach algebras which are the group algebra L 1 (G) and the measure algebra M (G) on G, concentrating on their second dual algebras. As a preliminary we shall study the second dual C0(Ω) of the C * -algebra C0(Ω) for a locally compact space Ω, recognizing this space as C( Ω), where Ω is the hyper-Stonean envelope of Ω.We shall study the C * -algebra of B b (Ω) of bounded Borel functions on Ω, and we shall determine the exact cardinality of a variety of subsets of Ω that are associated with B b (Ω).We shall identify the second duals of the measure algebra (M (G), ) and the group algebra (L 1 (G), ) as the Banach algebras (M ( G), 2 ) and (M (Φ), 2 ), respectively, where 2 denotes the first Arens product and G and Φ are certain compact spaces, and we shall then describe many of the properties of these two algebras. In particular, we shall show that the hyper-Stonean envelope G determines the locally compact group G. We shall also show that ( G, 2 ) is a semigroup if and only if G is discrete, and we shall discuss in considerable detail the product of point masses in M ( G). Some important special cases will be considered.We shall show that the spectrum of the C * -algebra L ∞ (G) is determining for the left topological centre of L 1 (G) , and we shall discuss the topological centre of the algebra (M (G) , 2 ).