Shock compression-induced enhancement of stimulated Raman scattering in heavy water

Forward stimulated Raman scattering and backward stimulated Raman scattering (BSRS) are measured when an intense 532 nm nanosecond pulsed laser is focused into water and heavy water. The investigation reveals a significant observation: the formation of the ice VII structure exclusively occurs in the backward direction when optical breakdown takes place, provided that the input energy falls below 90 mJ for liquid water or 75 mJ for heavy water. This phase transition is attributed to secondary shock compression, which comes from energy transfer and compression between the BSRS in plasmas with the pump laser. The optical breakdown experiment under pre-pressure reveals that the shock compression in the back direction is approximately 2.3 times that of the forward direction. This research is useful for shock compression and dynamics in plasmas.

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Highly efficient stimulated Raman scattering at the air–heavy water interface

Dou,

Li,

Sun

et al. 2024

Applied Physics Letters

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In this study, we conducted a detailed exploration of stimulated Raman scattering (SRS) in heavy water (D2O), focusing specifically on its behavior at the air–D2O interface. The analysis revealed discernible SRS characteristic peaks corresponding to different vibrational modes, showing a 3.31-fold reduction in the SRS threshold at the air–D2O interface. Notably, we achieved a remarkable 6.83% energy conversion efficiency, approximately 3.36 times higher than the 2.03% efficiency observed in bulk D2O. Through cascaded Raman scattering and Raman-enhanced four-wave mixing (FWM) processes, up to third-order Stokes and corresponding anti-Stokes SRS were obtained in an unprecedented manner at a low pump energy of 8.26 mJ. Additionally, distinctive conical spatial structures of Stokes and anti-Stokes generated at air–D2O interface were attributed to Raman-enhanced FWM processes. Our investigation into the temporal behavior of SRS pulses revealed a unique mechanism: the initial decline of pump pulse was due to SRS-induced pump energy loss and heat dissipation, while the behavior of latter half resulted from non-uniform refractive index, causing self-defocusing and inhibiting the sustained generation of SRS. Our study sheds light on the development of multi-wavelength and significant frequency shift Raman lasers, offering valuable perspectives for future research endeavors.

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Shock compression-induced enhancement of stimulated Raman scattering in heavy water

Cited by 5 publications

References 31 publications

Intermolecular competition regulates hydrogen bond reorientation in DMSO-Water: Insights from Raman scattering

Intermolecular competition regulates hydrogen bond reorientation in DMSO-Water: Insights from Raman scattering

Induction of ice VII structure with secondary shock compression by backward Raman scattering in plasmas

Highly efficient stimulated Raman scattering at the air–heavy water interface

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