The results of experimental study of the characteristics of a two wave UV-VUV lamp on a mixture of argon and freon vapors (CCl 4 ) with pumping by a nanosecond barrier discharge are presented. The spectral characteristics of the radiator in the wavelength range of 160-300 nm and the current and voltage oscillo grams have been studied. The intensity of the radiation of the 175 nm ArCl (B → X) and 258 nm Cl 2 (D' → A') bands were optimized during the variation of pressure and partial composition of the working mixture Ar-CCl 4 , and also the conditions of the ignition of the nanosecond discharge with two dielectric barriers. The main processes of the formation of the argon chloride molecule have been considered in the barrier discharge on the basis of the Ar-CCl 4 mixture.