The volumetric instability of alkali-activated slag (AAS) binders has raised concerns and impeded the acceptance of this Portland cement-free material. The objective of present work is to characterize the influence of drying rate on drying shrinkage behavior of alkali-activated slag mortars to better understand the mechanisms responsible for its large shrinkage deformation. A series of four AAS mortar mixtures with varying activator composition, as well as a reference Portland cement mortar was cast and dried at different relative humidities, i.e. 30%, 50%, 70% and 85% RH. Drying took place inside nitrogen purged environmental chambers, for the purpose of eliminating the contribution of carbonation to the total volumetric change of AAS. The shrinkage and corresponding mass loss of 1.27cm ×1.27cm ×12.7cm prisms were measured as a function of time. The results show that shrinkage of AAS varies largely depending on the drying rate, i.e. ambient RH. Interestingly, even though the drying mass loss increases with reducing the RH, the magnitude of shrinkage is the largest for samples stored at 50% and 70% RH, depending on the mixture type. Possible causes of these irregular behaviors are discussed. It is concluded that the drying rate has a much more significant influence on AAS than on OPC, which implies a more complicated shrinkage mechanism for AAS samples stored at various relative humidities.