We report muon spin rotation measurements on a single crystal of the marginal type-II superconductor V. The measured internal magnetic field distributions are modeled assuming solutions of the Ginzburg-Landau (GL) equations for an ideal vortex lattice obtained using (i) an iterative procedure developed by E.H. Brandt, Phys. Rev. Lett. 78, 2208Lett. 78, (1997 and (ii) a variational method. Both models yield qualitatively similar results. The magnetic penetration depth λ and the GL coherence length ξ determined from the data analysis exhibit strong field dependences, which are attributed to changes in the electronic structure of the vortex lattice. The zero-field extrapolated values of λ and the GL parameter κ agree well with values obtained by other experimental techniques that probe the Meissner state.