Fracture toughness enhancement of ceramic materials through multilayered ceramic composites has been developed since 1990. Toughening mechanisms are based mainly on delamination, deflection, bifurcation or crack arrest effect. Delamination and crack deflection occur by means of weak interfaces. Bifurcation (and deflection as well) and crack arrest effects are result of residual stresses arising from the thermal expansion coefficient mismatch or phase transformation on alternating layers. The main manufacturing methods of these composites are slip casting of two ceramic materials, and stacking and pressing of ceramic tapes obtained by tape casting or rolling technics, followed by suitable sintering process. This review aims to present general aspects of research performed around the theme so far. It is verified that occurs the enhancement of ceramic toughness and reliability with this technic, so it is possible to enlarge its range of application in engineering.