The symmetry principle has significant guiding value in vehicle dynamics modeling and motion control. In complex driving scenarios, there are problems of low accuracy and large time delay in the trajectory tracking control of unmanned ground vehicles. In order to solve this problem and improve the motion control of unmanned ground vehicles, a vehicle coordination control method based on chaotic particle swarm optimization (CPSO) and model predictive control (MPC) algorithms is proposed. To achieve coordinated control of vehicle trajectory tracking and yaw stability, a model predictive controller was designed with the objective of minimizing trajectory tracking errors and yaw stability tracking errors. The required front wheel angle and yaw torque control variables were obtained by solving nonlinear constraint optimization. At the same time, considering the problems of low computational efficiency, high solving time, and local optimization in model predictive control, a chaotic particle swarm optimization algorithm is introduced to solve the optimization constraint problem within model predictive control, thereby effectively improving the computational efficiency and accuracy of the model predictive trajectory tracking controller. The results show that compared with MPC, the multi-objective function optimization solution time and vehicle lane changing time of CPSOMPC improved by 24.51% and 7.21%, respectively, which indicates the coordinated control method that combines the CPSO and MPC algorithms can effectively improve trajectory tracking performance while ensuring vehicle lateral stability.