Silicalite Membrane for Separation of Acetic Acid / Water Mixture

Sano, Tsuneji; Ejiri, Shigeyuki; Hasegawa, Masaru; Kawakami, Yusuke; Enomoto, Nobuo; Tamai, Yoshinori; Yanagishita, Hiroshi

doi:10.1246/cl.1995.153

Cited by 24 publications

(6 citation statements)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…An elusive but highly rewarding goal is the fabrication of zeolite films for selective membranes, electrodes, sensors, and optoelectronic devices . Recently, a variety of techniques tailored to specific applications has emerged (postsynthesis preparations − as well as in situ film deposition − ); however, to date, no general preparative methods exist . Here we report on a new processing scheme which involves the use of zeolite nanosols (colloidal suspensions of zeolite nanoparticles) for film casting, combined with controlled secondary growth of the nanoparticles.…”

mentioning

confidence: 99%

Preparation of an Asymmetric Zeolite L Film

1996

View full text Add to dashboard Cite

show abstract

mentioning

confidence: 99%

Preparation of an Asymmetric Zeolite L Film

1996

View full text Add to dashboard Cite

show abstract

“…Finally, the pervaporation of acetic acid/water mixtures was studied with silicalite/ steel membranes, and preferred permeation of acetic acid was observed. 58 Intensive recent efforts have also focused on separations with MFI-type membranes on ceramic supports. Porous alumina has been the most popular support for these purposes.…”

Section: Separations With Supported and Free-standing Zeolite Membran...mentioning

confidence: 99%

Synthesis and Applications of Molecular Sieve Layers and Membranes

1996

View full text Add to dashboard Cite

Strategies for the preparation of zeolite molecular sieve membranes and layers on different substrates are reviewed. Membranes (and continuous thin films) have been synthesized with ZSM-5 (MFI) type molecular sieves and other zeolites, either as free-standing specimens, grown on various supports according to several schemes, or embedded in polymer matrices. The membranes have been studied for molecule-selective separations and for catalytic reactions. Layers of presynthesized molecular sieves have been deposited by means of solgel matrixes and other bonding agents, molecular attachment layers, and via sputtering or laser ablation techniques. The resulting nanoporous layers have been applied in highly selective sensors, for the alignment of NLO chromophores and for molecular separations. Finally, oriented molecular sieve layers have been grown on self-assembled organic monoand multilayers presenting phosphonate groups at the interface. Mixed phosphonate/alkyl films show profound effects on the surface crystallization of metallophosphate molecular sieves. MFI type zeolites have also been grown through the vapor phase on alkylammoniummodified gold substrates.

show abstract

“…Many research groups in different countries are working in this field and some methods are proposed in the literature for the separation and recovery of acetic acid from different waste sources [3][4][5][6][7][8][9][10][11]. Most of these processes are concerned to an aqueous solution that does not contain high concentration of inorganic acids.…”

Section: Introductionmentioning

confidence: 99%