Composites with a bulk metallic glass matrix were synthesized and characterized. This was made possible by the recent development of bulk metallic glasses that exhibit high resistance to crystallization in the undercooled liquid state. In this letter, experimental methods for processing metallic glass composites are introduced. Three different bulk metallic glass forming alloys were used as the matrix materials. Both ceramics and metals were introduced as reinforcement into the metallic glass. The metallic glass matrix remained amorphous after adding up to a 30 vol% fraction of particles or short wires. X-ray diffraction patterns of the composites show only peaks from the second phase particles superimposed on the broad diffuse maxima from the amorphous phase. Optical micrographs reveal uniformly distributed particles in the matrix. The glass transition of the amorphous matrix and the crystallization behavior of the composites were studied by calorimetric methods. © 1997 American Institute of Physics. ͓S0003-6951͑97͒02852-0͔Recently there has been considerable scientific and industrial interest in a variety of metal matrix composites as a way to improve mechanical properties compared to unreinforced alloys.1-3 Those materials are made by reinforcing alloys with long or short fibers, whiskers, or particles. Continuously reinforced composites provide maximum strength and stiffness in one direction but are anisotropic.4 Discontinuously reinforced metal matrix composites have been demonstrated to offer essentially isotropic properties with substantial improvements in strength and stiffness relative to those available with unreinforced materials. 5,6 Particulate composites have the further advantages of being machinable and workable using many conventional processing techniques. Many metals and ceramics have been considered as possible matrix materials. The most studied metal matrix for application at temperatures below 450°C is aluminum.7 Titanium has been extensively studied from the perspective of higher-temperature applications. 8 In this work, bulk metallic glasses were used as matrices reinforced with refractory ceramics, ductile metal particles, or short wires. This was made possible by the use of recently reported multicomponent alloys that exhibit an extremely high glass forming ability, e.g., La-Al-Ni, 9 Zr-Al-Cu-Ni, 10 and Zr-Ti-Cu-Ni-Be.
11In the work described here, Zr-Ti-Cu-Ni ͑Ref. 12͒ and Zr-Ti͑Nb͒-Al-Cu-Ni ͑Ref. 13͒ alloys, which show extraordinary glass forming ability, were used as the matrix. These bulk metallic glasses have promising properties such as high yield strength and a high elastic strain limit combined with relatively high fracture toughness, fatigue, and corrosion resistance. 14-17 However, they have little ductility in tension. This lack of tensile ductility could be an important drawback in many applications. Thus, one of the motivations for adding second phase particles to the metallic glass was to hinder propagation of shear bands and encourage the formation of multiple shear bands...