Silicone rubber films functionalized with poly(acrylic acid) nanobrushes for immobilization of gold nanoparticles and photothermal therapy

Cabana, Sonia Engroba; Lecona-Vargas, C. Sofía; Meléndez‐Ortiz, H. Iván; Contreras-García, Angel; Barbosa, Sílvia; Taboada, Pablo; Magariños, Beatríz; Bucio, Emilio

doi:10.1016/j.jddst.2017.04.006

Cited by 41 publications

(31 citation statements)

References 49 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Interestingly, Figure a revealed that AuNP‐loaded chitosan polymeric films prepared by solvent casting method exhibited significantly ( p < 0.05) greater burst strength and skin adhesion strength as well as better antibacterial activity against Staphylococcus aureus and Escherichia coli , compared with respective blank films, by taking the advantage of AuNP‐enforced mechanical property improvements . Figure b showed the uniformly immobilizing AuNPs onto silicone rubber (SR) film grafted with poly(acrylic acid) (PAAc) chains, which exploited the plasmon resonance properties for the photothermal killing of adhered bacteria . PAAc brushes on SR films served as a space to catch gold ions and reduce them to be AuNPs for photothermal antibacterials, which represented an easy and cost‐effective approach for medical device surface modification.…”

Section: Applicationmentioning

confidence: 99%

“…b) Polymeric silicone rubber (SR) films functionalized with poly(acrylic acid) nanobrushes for immobilization of gold salt for in situ formation of AuNPs@polymeric film as well as its ability to inhibit the bacterial S. aureus growth due to the photothermal behavior of AuNPs under 514 nm laser radiation. Reproduced with permission . Copyright 2017, Elsevier.…”

Section: Applicationmentioning

confidence: 99%

See 1 more Smart Citation

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Luo

et al. 2018

Macromol. Rapid Commun.

View full text Add to dashboard Cite

Gold nanoparticles (AuNPs), with elegant thermal, optical, or chemical properties due to quantum size effects, may serve as unique species for therapeutic or diagnostic applications. It is worth mentioning that their small size also results in high surface activity, leading to significantly impaired stability, which greatly hinders their biomedical utilizations. To overcome this problem, various types of macromolecular materials are utilized to anchor AuNPs so as to achieve advanced synergistic effect by dispersing, protecting, and stabilizing the AuNPs in polymeric-Au hybrid self-assemblies. In this review, the most recent development of polymer-AuNP hybrid systems, including AuNPs@polymeric nanoparticles, AuNPs@polymeric micelle, AuNPs@polymeric film, and AuNPs@polymeric hydrogel are discussed with respect to their different synthetic strategies. These sophisticated materials with diverse functions, oriented toward biomedical applications, are further summarized into several active domains in the areas of drug delivery, gene delivery, photothermal therapy, antibacterials, bioimaging, etc. Finally, the possible approaches for future design of multifunctional polymer-AuNP hybrids by combining hybrid chemistry with biological interface science are proposed.

show abstract

Section: Applicationmentioning

confidence: 99%

Section: Applicationmentioning

confidence: 99%

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Luo

et al. 2018

Macromol. Rapid Commun.

View full text Add to dashboard Cite

show abstract

“…In the biomedical field, the one‐pot preparation of polymer gels or solid medical devices that can induce by themselves the spontaneous formation of Au NPs is attracting growing interest . In the absence of catalyzers and other reagents, the composite system is formed in one step and does not require downstream purification processes . In this regard, poly(ethylene oxide)‐poly(propylene oxide)‐poly(ethylene oxide) (PEO‐PPO‐PEO) copolymers, known as poloxamers, and other related copolymers such as poloxamines have been shown able to induce nucleation of gold particles and drive their controlled growth not only as spherical nanoparticles but also toward a variety of anisotropic nanostructures .…”

Section: Introductionmentioning

confidence: 99%

Poly(vinyl alcohol) triggers Au nanoparticles formation for near‐infrared radiation‐responsive gels and nanofibers

Álvarez-Lorenzo

Mayo‐Olveira

Barbosa

et al. 2019

J of Applied Polymer Sci

Self Cite

View full text Add to dashboard Cite

The capability of poly(vinyl alcohol) (PVA) to reduce noble metal ions and, in turn, to prepare one‐step hybrid systems that exhibit near‐infrared radiation (NIR) light‐responsiveness has been barely explored. The aim of this work was to elucidate whether gold nanoparticles (Au NPs) could be spontaneously formed in PVA gels suitable to be used as syringeable depots or to prepare electrospun nanofibers. To check the hypothesis of that the gold counterion may play a role in the Au NPs formation process, two different gold salts (HAuCl4 and AuAc3) were used. Localized surface plasmon resonance bands were monitored during the incubation of PVA‐gold salt gels, and the photoresponsive capability of the newly formed Au NPs inside gels was investigated during laser irradiation at 808 nm. HET‐CAM assay suggested good biocompatibility. Then, the feasibility of producing electrospun hybrid PVA‐based mats that exhibit light‐responsive photothermal features was explored here for the first time. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48811.

show abstract

“…PAA is a biodegradable vinylic‐based aliphatic acid regularly prepared by polymerization of AA in the presence of ammonium persulfate (APS) as an initiator . Based on its biodegradable, low‐toxicity, and high biocompatible nature, PAA is broadly applied in packaging, cleaning agents, and biomedical applications . To increase its biodegradability and hydrophilicity, PAA is grafted with a biopolymer such as dextran, starch, cellulose, or chitosan.…”

Section: Introductionmentioning

confidence: 99%

Nano‐CaCO₃‐embodied polyacrylicacid/dextran nanocomposites for packaging applications

Sethy

Prusty

Mohapatra

et al. 2019

J of Applied Polymer Sci

View full text Add to dashboard Cite

In present work, Dextran-grafted poly(acrylic acid) [D-g-PAA] hybrid nanocomposites are prepared in aqueous medium with reinforcement of various concentrations of nano-CaCO 3 (CC) through in situ polymerization of acrylic acid. The chemical interactions between filler and polymeric matrix are studied by Fourier transform infrared spectroscopy. The structural properties of the D-g-PAA/CC nanocomposite are investigated by X-ray diffraction, field-emission scanning electron microscopy, and high-resolution transmission electron microscopy. The aloe vera plant structured morphology is noticed by interaction of dextran with PAA, where CC nanoparticles are embedded within the D-g-PAA matrix. The thermal stability of the D-g-PAA/CC hybrid nanocomposites is enhanced by the incorporation of nano-CC. The tensile properties and antibacterial behavior of D-g-PAA/CC hybrid nanocomposites are also increased by incorporation of nano-CC. The oxygen barrier behavior of hybrid nanocomposites is increased by 11-folds with a reinforcement of 8 wt % of nano-CC. Herein, the incorporation of nano-CC enhances the oxygen barrier, thermal, and antimicrobial properties of the D-g-PAA matrix by which the synthesized material is suitable for packaging applications.

show abstract

Silicone rubber films functionalized with poly(acrylic acid) nanobrushes for immobilization of gold nanoparticles and photothermal therapy

Cited by 41 publications

References 49 publications

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Poly(vinyl alcohol) triggers Au nanoparticles formation for near‐infrared radiation‐responsive gels and nanofibers

Nano‐CaCO₃‐embodied polyacrylicacid/dextran nanocomposites for packaging applications

Contact Info

Product

Resources

About

Silicone rubber films functionalized with poly(acrylic acid) nanobrushes for immobilization of gold nanoparticles and photothermal therapy

Cited by 41 publications

References 49 publications

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Recent Progress in Macromolecule‐Anchored Hybrid Gold Nanomaterials for Biomedical Applications

Poly(vinyl alcohol) triggers Au nanoparticles formation for near‐infrared radiation‐responsive gels and nanofibers

Nano‐CaCO3‐embodied polyacrylicacid/dextran nanocomposites for packaging applications

Contact Info

Product

Resources

About

Nano‐CaCO₃‐embodied polyacrylicacid/dextran nanocomposites for packaging applications