2005
DOI: 10.1016/j.jfluchem.2005.07.002
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Silver compounds in synthetic chemistry

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Cited by 15 publications
(23 citation statements)
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“…Neat AgC 6 F 5 . As illustrated in Scheme 2,5 solvent-free, pure AgC 6 F 5 was obtained from Li[B (C 6 F 5 ) 4 ] and AgF, which were first combined and suspended in dichloromethane prior to sonification in an ultrasonic bath at 40−60°C for 8 h. The resulting grayish suspension was filtered, resulting in a clear, brownish solution. Removal of CH 2 Cl 2 followed by extraction of B(C 6 F 5 ) 3 by washing with n-hexane yielded an offwhite solid AgC 6 F 5 (yield: 90%, T dec = 276°C).…”
Section: H 5 N) 3 ][Aumentioning
confidence: 99%
See 1 more Smart Citation
“…Neat AgC 6 F 5 . As illustrated in Scheme 2,5 solvent-free, pure AgC 6 F 5 was obtained from Li[B (C 6 F 5 ) 4 ] and AgF, which were first combined and suspended in dichloromethane prior to sonification in an ultrasonic bath at 40−60°C for 8 h. The resulting grayish suspension was filtered, resulting in a clear, brownish solution. Removal of CH 2 Cl 2 followed by extraction of B(C 6 F 5 ) 3 by washing with n-hexane yielded an offwhite solid AgC 6 F 5 (yield: 90%, T dec = 276°C).…”
Section: H 5 N) 3 ][Aumentioning
confidence: 99%
“…Removal of CH 2 Cl 2 followed by extraction of B(C 6 F 5 ) 3 by washing with n-hexane yielded an offwhite solid AgC 6 F 5 (yield: 90%, T dec = 276°C). With pure AgC 6 F 5 in hand, we were able to study the solvation of AgC 6 F 5 in differently substituted arenes (arene = benzene (b), toluene (tol), ethylbenzene (eb), 1,2-dimethylbenzene (12dm), 1,3-dimethylbenzene (13dm), 1,4-dimethylbenzene (14dm), 1,2,3-trimethylbenzene (123tm), 1,2,4-trimethylbenzene (124tm), 1,3,5-trimethylbenzene (135tm), 1,2,3,5-tetramethylbenzene (1235tem), 1,2,4,5-tetramethylbenzene (1245tem), 1,2,3,4,5-pentamethylbenzene (12345 pm).…”
Section: H 5 N) 3 ][Aumentioning
confidence: 99%
“…In a recent report, we published a convenient and absolutely selective method for the preparation of 2,3,4,5,6-pentafluorophenones starting from carboxylic acid chlorides and pentafluorophenyl silver under moderate conditions [16]. A selective route to prepare trifluoromethyl silver involves the reaction of trimethyl(trifluoromethyl)silane with silver(I) fluoride in an appropriate solvent such as acetonitrile, propionitrile or DMF at room temperature [17].…”
Section: Introductionmentioning
confidence: 99%
“…Compound 36 has the open-chain structure, because the 13 C NMR spectrum contains two signals of carbonyl groups at 178.7 ppm (RCOAr) and 161.9 ppm (COOH); assignment of the signals was made by analogy with perfluorinated benzophenone [14] and phthalic acid [15]. According to the 19 F NMR spectrum, CDCl 3 solution of compound 19 contains cyclic 19 and open-chain 19a forms in the ratio 87:13, respectively.…”
Section: Structure Of Compoundsmentioning
confidence: 99%