Silver-Doped Titania Modified Carbon Electrode for Electrochemical Studies of Furantril

Abstract

An electrochemical method for the determination of an antrallinic acid derivative based on nanoparticles modified electrode was studied through cyclic and differential pulse voltammetry. Modification of electrode with silver-doped titania nanoparticles enhanced the peak current for the electro-oxidation of Furantril. The silver-doped titania nanoparticles were prepared by simple wet chemical methods and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffractometer (XRD). Silver-doped TiO 2 voltamogramms suggested that pH 5.0 was suitable for electrochemical investigation of furantril. Rate constant, diffusion coefficient, electrode process and number of electrons involved were calculated. Based on these investigations a feasible mechanism for electrode reaction was presented. Limit of detection and quantification were found to be 1.98 nM and 6.6 nM respectively.

Determination of Carmoisine onto Carbon‐Paste Electrode Modified by Silica Impregnated with Cetylpyridinium Chloride

“…When developing new voltammetric sensors, various modification methods can be used to increase the sensitivity of analyte determination. For example, you can use the electrochemical pretreated electrodes, carbon nanomaterials, metal nanoparticles and their oxides, as well as materials that increase the sorption of analyte on the surface of the electrode…”

“…Comparative characteristics of the proposed sensors are presented in Table 1 When developing new voltammetric sensors, various modification methods can be used to increase the sensitivity of analyte determination. For example, you can use the electrochemical pretreated electrodes, [18][19][20][21] carbon nanomaterials, [16,[22][23][24] metal nanoparticles and their oxides, [25][26][27][28] as well as materials that increase the sorption of analyte on the surface of the electrode. [29,30] Cetylpyridinium chloride is more cost-effective CPE modifier than carbon nanomaterials.…”

Voltammetric Study and Rapid Quantification of Resorcinol in Hair Dye and Biological Samples Using Ultrasensitive Maghemite/MWCNT Modified Carbon Paste Electrode

“…Bulk modification involves mechanical admixing of modifier into CP bulk. It is one of the simplest modification methods in terms of ease of preparation of modified electrode . M/MWCNT/MCPE offered the advantages of, improved sensing qualities which contribute to better selectivity, sensitivity as well as properties such as anti‐fouling and anti‐interference .…”

Determination of Riboflavin at Carbon Nanotube Paste Electrodes Modified with an Anionic Surfactant

“…Which were found to be extremely sensitive to acids and basis media. The drive of these modifiers is due to the reducing over potential for the reduction/oxidation of analytes in contrast with the unmodified electrode . The Objective of the current study is that carbon nanotube paste electrode modified with SLS for voltammetric determination of the RF with wavering parameters like scan rate, pH, and concentration in 0.2 M PBS (pH 7.0).…”

“…The drive of these modifiers is due to the reducing over potential for the reduction/oxidation of analytes in contrast with the unmodified electrode. [21][22][23][24][25][26][27][28][29][30][31][32][33][34][35] The Objective of the current study is that carbon nanotube paste electrode modified with SLS for voltammetric determination of the RF with wavering parameters like scan rate, pH, and concentration in 0.2 M PBS (pH 7.0). To best of our information, there was no voltammetric sensor based on SLSMCNTPE for the determination of RF.…”