Silver(I) diaquanickel(II)catena-borodiphosphate(V) hydrate, (Ag_0.57Ni_0.22)Ni(H₂O)₂[BP₂O₈]·0.67H₂O

Abstract

Key indicators: single-crystal X-ray study; T = 296 K; mean (O-B) = 0.003 Å; disorder in main residue; R factor = 0.028; wR factor = 0.071; data-to-parameter ratio = 26.5.The structure framework of the title compound, (Ag 0.57 4 and PO 4 tetrahedra arranged around the 6 5 screw axes. The vertex-sharing BO 4 and PO 4 tetrahedra form a spiral ribbon of four-membered rings in which BO 4 and PO 4 groups alternate. The ribbons are connected through slightly distorted NiO 4 (H 2 O) 2 octahedra, four O atoms of which belong to the phosphate groups. The resulting three-dimensional framework is characterized by hexagonal channels running along [001]. However, the main difference between the structures of these two compounds lies in the filling ratio of Wyckoff positions 6a and 6b in the tunnels. Indeed, in this work, the refinement of the occupancy rate of sites 6a and 6b shows that the first is occupied by water at 67% and the second is partially occupied by 56.6% of Ag and 21.6% of Ni. In the AgMg(H 2 O) 2 [BP 2 O 8 ]ÁH 2 O structure, these two sites are completely occupied by H 2 O and Ag + , respectively. The title structure is stabilized by O-HÁ Á ÁO hydrogen bonds between water molecules and O atoms that are part of the helices. Related literature